Regioselective hydrosilylation of epoxides catalysed by nickel(ii) hydrido complexes.
作者信息
Wenz Jan, Wadepohl Hubert, Gade Lutz H
机构信息
Anorganisch-Chemisches Institut, University of Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
出版信息
Chem Commun (Camb). 2017 Apr 13;53(31):4308-4311. doi: 10.1039/c7cc01655g.
PMID:28367579
Abstract
Bench-stable nickel fluoride complexes bearing NNN pincer ligands have been employed as precursors for the regioselective hydrosilylation of epoxides at room temperature. A nickel hydride assisted epoxide opening is followed by the cleavage of the newly formed nickel oxygen bond by σ-bond metathesis with a silane.
摘要
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