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金属有机骨架材料(MOFs)与聚合物的杂化。

Hybridization of MOFs and polymers.

机构信息

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

出版信息

Chem Soc Rev. 2017 Jun 6;46(11):3108-3133. doi: 10.1039/c7cs00041c.

Abstract

Metal-organic frameworks (MOFs) have received much attention because of their attractive properties. They show great potential applications in many fields. An emerging trend in MOF research is hybridization with flexible materials, which is the subject of this review. Polymers possess a variety of unique attributes, such as softness, thermal and chemical stability, and optoelectrical properties that can be integrated with MOFs to make hybrids with sophisticated architectures. Hybridization of MOFs and polymers is producing new and versatile materials that exhibit peculiar properties hard to realize with the individual components. This review article focuses on the methodology for hybridization of MOFs and polymers, as well as the intriguing functions of hybrid materials.

摘要

金属有机骨架(MOFs)因其诱人的特性而备受关注。它们在许多领域具有巨大的潜在应用。MOF 研究中的一个新兴趋势是与柔性材料的杂化,这是本综述的主题。聚合物具有多种独特的属性,如柔软性、热稳定性和化学稳定性以及光电性能,这些性能可以与 MOFs 结合,制造具有复杂结构的杂化物。MOFs 和聚合物的杂化产生了新的多功能材料,这些材料表现出独特的性质,难以用单个组件来实现。本文综述了 MOFs 和聚合物的杂化方法以及杂化材料的有趣功能。

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