有机催化原子转移自由基聚合：催化剂设计与性能展望
Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance.
作者信息
Theriot Jordan C, McCarthy Blaine G, Lim Chern-Hooi, Miyake Garret M
机构信息
Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, Colorado, 80309, United States.
Department of Chemistry and Biochemistry, Materials Science and Engineering Program, University of Colorado Boulder, Boulder, Colorado, 80309, United States.
出版信息
Macromol Rapid Commun. 2017 Jul;38(13). doi: 10.1002/marc.201700040. Epub 2017 Apr 3.
Abstract
The recent development of organocatalyzed atom transfer radical polymerization (O-ATRP) represents a significant advancement in the field of controlled radical polymerizations. A number of classes of photoredox catalysts have been employed thus far in O-ATRP. Analysis of the proposed mechanism gives insight into the relevant photophysical and chemical properties that determine catalyst performance. Discussion of each of the classes of O-ATRP catalysts highlights their previous uses, their roles in the development of O-ATRP, and the distinctive properties that govern their polymerization behavior, leading to a set of design principles for O-ATRP catalysts. Remaining challenges for O-ATRP are presented, as well as prospects for further improvement in the application scope of O-ATRP.
摘要
有机催化原子转移自由基聚合（O-ATRP）的最新进展代表了可控自由基聚合领域的一项重大进步。迄今为止，多种类型的光氧化还原催化剂已被应用于O-ATRP。对所提出的机理进行分析，有助于深入了解决定催化剂性能的相关光物理和化学性质。对各类O-ATRP催化剂的讨论突出了它们以前的用途、在O-ATRP发展中的作用以及支配其聚合行为的独特性质，从而得出了一套O-ATRP催化剂的设计原则。文中还介绍了O-ATRP面临的剩余挑战，以及进一步扩大O-ATRP应用范围的前景。
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