Shimada Kunio
Faculty of Symbiotic Systems Sciences, Fukushima University, 1 Kanayagawa, Fukushima 960-1296, Japan.
Sensors (Basel). 2017 Apr 4;17(4):767. doi: 10.3390/s17040767.
Many sensors require mechanical durability to resist immense or impulsive pressure and large elasticity, so that they can be installed in or assimilated into the outer layer of artificial skin on robots. Given these demanding requirements, we adopted natural rubber (NR-latex) and developed a new method (NM) for curing NR-latex by the application of a magnetic field under electrolytic polymerization. The aim of the present work is to clarify the new manufacturing process for NR-latex embedded with magnetic compound fluid (MCF) as a conductive filler, and the contribution of the optimization of the new process for sensor. We first clarify the effect of the magnetic field on the enhancement of the NR-latex MCF rubber created by the alignment of magnetic clusters of MCF. Next, SEM, XRD, Raman spectroscopy, and XPS are used for morphological and microscopic observation of the electrolytically polymerized MCF rubber, and a chemical approach measuring pH and ORP of the MCF rubber liquid was used to investigate the process of electrolytic polymerization with a physical mode. We elucidate why the MCF rubber produced by the NM is enhanced with high sensitivity and long-term stability. This process of producing MCF rubber by the NM is closely related to the development of a highly sensitive sensor.
许多传感器需要具备机械耐久性,以抵抗巨大或脉冲压力,并具有较大的弹性,以便能够安装在机器人的人造皮肤外层或与之融合。鉴于这些苛刻的要求,我们采用了天然橡胶(NR-乳胶),并开发了一种新方法(NM),即在电解聚合过程中通过施加磁场来固化NR-乳胶。本工作的目的是阐明嵌入磁性复合流体(MCF)作为导电填料的NR-乳胶的新制造工艺,以及新工艺优化对传感器的贡献。我们首先阐明磁场对由MCF磁性簇排列产生的NR-乳胶MCF橡胶增强的影响。接下来,使用扫描电子显微镜(SEM)、X射线衍射(XRD)、拉曼光谱和X射线光电子能谱(XPS)对电解聚合的MCF橡胶进行形态和微观观察,并采用化学方法测量MCF橡胶液体的pH值和氧化还原电位(ORP),以物理模式研究电解聚合过程。我们阐明了为什么通过NM生产的MCF橡胶具有高灵敏度和长期稳定性。通过NM生产MCF橡胶的这一过程与高灵敏度传感器的开发密切相关。