Liu Bo, Zhang Rui, Pan Chun-Yang, Jiang Hai-Long
School of Light Industry and Chemical Engineering, Guangdong University of Technology , Guangzhou 510006, China.
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
Inorg Chem. 2017 Apr 17;56(8):4263-4266. doi: 10.1021/acs.inorgchem.7b00538. Epub 2017 Apr 5.
We herein report the first example of Li exchanged with both the guest HN(Me) cations located in the channels and the coordinated metal ions from an anionic metal-organic framework (MOF), leading to significant enhancement of the pore volume and gas sorption abilities of the exchanged MOF. Furthermore, both MOFs before and after Li exchange show good selective adsorption for CO over CH.
我们在此报告首例锂与位于通道中的客体 HN(Me) 阳离子以及来自阴离子金属有机框架（MOF）的配位金属离子进行交换的情况，这导致交换后的 MOF 的孔体积和气体吸附能力显著增强。此外，锂交换前后的两种 MOF 对 CO 均表现出优于 CH 的良好选择性吸附。
