Wang Xiangfu, Wang Ye, Marques-Hueso Jose, Yan Xiaohong
College of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing, 210023, People's Republic of China.
Institute of Sensors, Signals and Systems, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK.
Sci Rep. 2017 Apr 7;7(1):758. doi: 10.1038/s41598-017-00838-w.
This work presents a new method to effectively improve the optical temperature behavior of Er doped YO microtubes by co-doping of Tm or Ho ion and controlling excitation power. The influence of Tm or Ho ion on optical temperature behavior of YO:Er microtubes is investigated by analyzing the temperature and excitation power dependent emission spectra, thermal quenching ratios, fluorescence intensity ratios, and sensitivity. It is found that the thermal quenching of YO:Er microtubes is inhibited by co-doping with Tm or Ho ion, moreover the maximum sensitivity value based on the thermal coupled S/H levels is enhanced greatly and shifts to the high temperature range, while the maximum sensitivity based on F/F levels shifts to the low temperature range and greatly increases. The sensitivity values are dependent on the excitation power, and reach two maximum values of 0.0529/K at 24 K and 0.0057/K at 457 K for the YO:1%Er, 0.5%Ho at 121 mW/mm excitation power, which makes optical temperature measurement in wide temperature range possible. The mechanism of changing the sensitivity upon different excitation densities is discussed.
这项工作提出了一种通过共掺杂Tm或Ho离子并控制激发功率来有效改善掺铒YO微管光学温度行为的新方法。通过分析与温度和激发功率相关的发射光谱、热猝灭率、荧光强度比和灵敏度,研究了Tm或Ho离子对YO:Er微管光学温度行为的影响。研究发现,通过与Tm或Ho离子共掺杂可抑制YO:Er微管的热猝灭,此外,基于热耦合S/H能级的最大灵敏度值大幅提高并向高温范围移动,而基于F/F能级的最大灵敏度则向低温范围移动并大幅增加。灵敏度值取决于激发功率,对于在121 mW/mm激发功率下的YO:1%Er、0.5%Ho,在24 K时达到0.0529/K的两个最大值,在457 K时达到0.0057/K,这使得在宽温度范围内进行光学温度测量成为可能。讨论了在不同激发密度下灵敏度变化的机制。