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TiO纳米管层内CuInSe的电化学填充及后续光电化学研究。

Electrochemical Infilling of CuInSe within TiO Nanotube Layers and Subsequent Photoelectrochemical Studies.

作者信息

Das Sayantan, Sopha Hanna, Krbal Milos, Zazpe Raul, Podzemna Veronika, Prikryl Jan, Macak Jan M

机构信息

Center of Materials and Nanotechnologies Faculty of Chemical Technology University of Pardubice Nam. Cs. Legii 565 53002 Pardubice Czech Republic.

出版信息

ChemElectroChem. 2017 Mar;4(3):495-499. doi: 10.1002/celc.201600763. Epub 2017 Feb 8.

DOI:10.1002/celc.201600763
PMID:28392991
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5363378/
Abstract

Anodic self-organized TiO nanotube layers (with different aspect ratios) were electrochemically infilled with CuInSe nanocrystals with the aim to prepare heterostructures with a photoelectrochemical response in the visible light. The resulting heterostructure assembly was confirmed by field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). High incident photon-to-electron conversion efficiency values exceeding 55% were obtained in the visible-light region. The resulting heterostructures show promise as a candidate for solid-state solar cells.

摘要

通过电化学方法将阳极自组装的TiO纳米管层（具有不同的纵横比）用CuInSe纳米晶体填充，目的是制备在可见光下具有光电化学响应的异质结构。通过场发射扫描电子显微镜（FESEM）、透射电子显微镜（TEM）和X射线衍射（XRD）对所得的异质结构组件进行了确认。在可见光区域获得了超过55%的高入射光子到电子转换效率值。所得的异质结构有望成为固态太阳能电池的候选材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/ff07002827fb/CELC-4-495-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/de7f2dc2bb25/CELC-4-495-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/35d866d0c24e/CELC-4-495-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/050072d30d11/CELC-4-495-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/09c4f8a8f1c6/CELC-4-495-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/ff07002827fb/CELC-4-495-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/de7f2dc2bb25/CELC-4-495-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/35d866d0c24e/CELC-4-495-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/050072d30d11/CELC-4-495-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/09c4f8a8f1c6/CELC-4-495-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd25/5363378/ff07002827fb/CELC-4-495-g005.jpg

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