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从印度藜麦品种中分离出的淀粉的结构、热学和流变学特性。

Structural, thermal and rheological properties of starches isolated from Indian quinoa varieties.

作者信息

Jan Khan Nadiya, Panesar P S, Rana J C, Singh Sukhcharn

机构信息

Department of Food Engineering and Technology, Sant Longowal Institute of Engineering & Technology, (SLIET), (Deemed - University), Longowal, Sangrur, Punjab, India.

Head of Division, Plant Breeding, National Bureau of Plant Genetic Resources, New Delhi, India.

出版信息

Int J Biol Macromol. 2017 Sep;102:315-322. doi: 10.1016/j.ijbiomac.2017.04.027. Epub 2017 Apr 8.

DOI:10.1016/j.ijbiomac.2017.04.027
PMID:28396270
Abstract

In this study starches isolated from Indian quinoa varieties were examined for physicochemical, morphological, thermal and rheological properties. Among isolated starches V showed higher starch yield and lower purity (48.45% and 98.32%) than V (41.28 and 98.53%). The amylose content was higher for V (12.10%) than V (9.46%). Swelling powers and solubility of the starches increased with increasing temperature. Peak viscosity (386.4 RVU) was higher for V. In contrast V showed higher pasting temperature (72.85°C). Low setback viscosity of the starches suggests that they can be profitably used in frozen and refrigerated foods. Starch granules from both varieties were irregular, angular and polygonal in shape. The starch granule size obtained by SEM was 1.23μm for V and 1.19μm for V. Both starches showed a typical A-type diffractrometric pattern with varying crystallinity. Further V showed lower transition temperatures (To, Tp and Tc) than V. FTIR spectroscopy showed higher intensity and broader shape of V at OH stretch which can be due to its higher crystallinity. Increased interest is shown in quinoa starch because of its unique microcrystalline granules. Higher yield and purity values suggest that both varieties can be exploited for commercial starch utilization.

摘要

在本研究中,对从印度藜麦品种中分离出的淀粉进行了物理化学、形态、热学和流变学性质的研究。在分离出的淀粉中,V的淀粉产率较高,纯度较低(分别为48.45%和98.32%),而V的淀粉产率和纯度分别为41.28和98.53%。V的直链淀粉含量(12.10%)高于V(9.46%)。淀粉的膨胀力和溶解度随温度升高而增加。V的峰值粘度较高(386.4 RVU)。相比之下,V的糊化温度较高(72.85°C)。淀粉的低回生粘度表明它们可成功用于冷冻和冷藏食品。两个品种的淀粉颗粒形状不规则、呈角状和多边形。通过扫描电子显微镜获得的淀粉颗粒大小,V为1.23μm,V为1.19μm。两种淀粉均呈现典型的A型衍射图谱,结晶度不同。此外,V的转变温度(To、Tp和Tc)低于V。傅里叶变换红外光谱显示,V在羟基伸缩振动处的强度更高、峰形更宽,这可能是由于其结晶度较高。由于藜麦淀粉独特的微晶颗粒,人们对它的兴趣日益增加。较高的产率和纯度值表明这两个品种都可用于商业淀粉利用。

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