Farzad Somayeh, Mandegari Mohsen Ali, Guo Miao, Haigh Kathleen F, Shah Nilay, Görgens Johann F
Department of Process Engineering, Stellenbosch University, Stellenbosch, 7600 South Africa.
Department of Chemical Engineering, Imperial College London, London, SW7 2AZ UK.
Biotechnol Biofuels. 2017 Apr 11;10:87. doi: 10.1186/s13068-017-0761-9. eCollection 2017.
Driven by a range of sustainability challenges, e.g. climate change, resource depletion and expanding populations, a circular bioeconomy is emerging and expected to evolve progressively in the coming decades. South Africa along with other BRICS countries (Brazil, Russia, India and China) represents the emerging bioeconomy and contributes significantly to global sugar market. In our research, South Africa is used as a case study to demonstrate the sustainable design for the future biorefineries annexed to existing sugar industry. Detailed techno-economic evaluation and Life Cycle Assessment (LCA) were applied to model alternative routes for converting sugarcane residues (bagasse and trash) to selected biofuel and/or biochemicals (ethanol, ethanol and lactic acid, ethanol and furfural, butanol, methanol and Fischer-Tropsch synthesis, with co-production of surplus electricity) in an energy self-sufficient biorefinery system.
Economic assessment indicated that methanol synthesis with an internal rate of return (IRR) of 16.7% and ethanol-lactic acid co-production (20.5%) met the minimum investment criteria of 15%, while the latter had the lowest sensitivity to market price amongst all the scenarios. LCA results demonstrated that sugarcane cultivation was the most significant contributor to environmental impacts in all of the scenarios, other than the furfural production scenario in which a key step, a biphasic process with tetrahydrofuran solvent, had the most significant contribution.
Overall, the thermochemical routes presented environmental advantages over biochemical pathways on most of the impact categories, except for acidification and eutrophication. Of the investigated scenarios, furfural production delivered the inferior environmental performance, while methanol production performed best due to its low reagent consumption. The combined techno-economic and environmental assessments identified the performance-limiting steps in the 2G biorefinery design for sugarcane industry and highlighted the technology development opportunities under circular bioeconomy context.
在一系列可持续发展挑战的推动下,例如气候变化、资源枯竭和人口增长,循环生物经济正在兴起,并有望在未来几十年逐步发展。南非与其他金砖国家(巴西、俄罗斯、印度和中国)代表了新兴生物经济,并对全球糖市场做出了重大贡献。在我们的研究中,南非被用作案例研究,以展示附属于现有制糖业的未来生物精炼厂的可持续设计。详细的技术经济评估和生命周期评估(LCA)被应用于模拟在能源自给自足的生物精炼厂系统中,将甘蔗残渣(蔗渣和蔗叶)转化为选定的生物燃料和/或生物化学品(乙醇、乙醇和乳酸、乙醇和糠醛、丁醇、甲醇和费托合成,并联产剩余电力)的替代路线。
经济评估表明,内部收益率(IRR)为16.7%的甲醇合成以及乙醇-乳酸联产(20.5%)满足15%的最低投资标准,而后者在所有情景中对市场价格的敏感度最低。LCA结果表明,在所有情景中,甘蔗种植对环境影响的贡献最大,但糠醛生产情景除外,在该情景中,一个关键步骤,即使用四氢呋喃溶剂的双相过程,贡献最为显著。
总体而言,在大多数影响类别上,热化学路线比生物化学途径具有环境优势,但酸化和富营养化除外。在所研究的情景中,糠醛生产的环境表现较差,而甲醇生产由于其试剂消耗低而表现最佳。综合技术经济和环境评估确定了甘蔗产业第二代生物精炼厂设计中的性能限制步骤,并突出了循环生物经济背景下的技术发展机会。