苯并菲类几何结构分子的碗状超分子组装
Synthesis and Bowl-in-Bowl Assembly of a Geodesic Phenylene Bowl.
机构信息
Department of Chemistry, The University of Tokyo, JST, ERATO, Isobe Degenerate π-Integration Project, Hongo 7-3-1, Bunkyo-ku, Tokyo, 113-0033, Japan.
Advanced Institute for Materials Research, Tohoku University, Aoba-ku, Sendai, 980-8577, Japan.
出版信息
Angew Chem Int Ed Engl. 2017 Jun 1;56(23):6511-6514. doi: 10.1002/anie.201702063. Epub 2017 Apr 12.
A phenylene multiring with a corannulenoidal skeleton was synthesized. Geodesic constraints over 20 phenylene panels resulted in its nanometer-sized, bowl-shaped molecular structure, which was unequivocally revealed by crystallographic analysis. The crystal structure also showed the presence of a bowl-in-bowl dimeric assembly, which was driven by entropic factors in solution.
合成了具有 corannulenoidal 骨架的苯并多环。超过 20 个苯环的测地线约束导致其具有纳米级的碗状分子结构，这一点通过晶体学分析得到了明确的揭示。晶体结构还显示了存在碗中碗二聚体组装，这是由溶液中的熵因素驱动的。
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