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用于光催化降解有机污染物的FeO/TiO磁性介孔复合材料的制备

Preparation of FeO/TiO magnetic mesoporous composites for photocatalytic degradation of organic pollutants.

作者信息

Zhang Hongfeng, He Xiu, Zhao Weiwei, Peng Yu, Sun Donglan, Li Hao, Wang Xiaocong

机构信息

College of Chemical Engineering and Material Science, Tianjin University of Science & Technology, Tianjin 300457, China E-mail:

College of Science, Tianjin University of Science & Technology, Tianjin 300457, China.

出版信息

Water Sci Technol. 2017 Apr;75(7-8):1523-1528. doi: 10.2166/wst.2017.002.

Abstract

FeO/TiO magnetic mesoporous composites were synthesized through a sol-gel method with tetra-n-butyl titanate as precursor and surfactant P123 as template. The as-prepared FeO/TiO composites were characterized by X-ray diffraction, diffuse reflectance spectroscopy, nitrogen adsorption-desorption isotherm and pore size distribution. The as-synthesized products were applied as photocatalysis for the degradation of Acid Black ATT and tannery wastewater under UV lamp irradiation. FeO/TiO-8 composites containing FeO of 8 wt% were selected as model catalysts. The optimal catalyst dosage was 3 g/L in this photocalytic system. The magnetic FeO/TiO composites possessed good photocatalytic stability and durability. This approach may provide a platform to prepare a magnetic composite to optimize the catalytic ability.

摘要

以钛酸四丁酯为前驱体、表面活性剂P123为模板,通过溶胶-凝胶法合成了FeO/TiO磁性介孔复合材料。采用X射线衍射、漫反射光谱、氮吸附-脱附等温线和孔径分布对所制备的FeO/TiO复合材料进行了表征。将合成产物用作光催化剂,在紫外灯照射下对酸性黑ATT和制革废水进行降解。选择含8 wt% FeO的FeO/TiO-8复合材料作为模型催化剂。在该光催化体系中,最佳催化剂用量为3 g/L。磁性FeO/TiO复合材料具有良好的光催化稳定性和耐久性。该方法可为制备磁性复合材料以优化催化性能提供一个平台。

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