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一种用于实现最长电子迁移自组装链（EMACs）的带有修饰萘啶酰胺的配体设计：十一镍金属链的首次单分子电导

A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string.

作者信息

Chen Po-Jung, Sigrist Marc, Horng Er-Chien, Lin Geng-Min, Lee Gene-Hsiang, Chen Chun-Hsien, Peng Shie-Ming

机构信息

Department of Chemistry and Centre for Emerging Material and Advanced Devices, National Taiwan University, Taipei 106, Taiwan.

出版信息

Chem Commun (Camb). 2017 Apr 25;53(34):4673-4676. doi: 10.1039/c7cc01831b.

DOI:10.1039/c7cc01831b
PMID:28405649
Abstract

Striding to extend the length of metal-atom strings, oligo-α-pyridylamino ligands are modulated with naphthyridyl moieties leading to the undeca-nickel mixed-valence complexes [Ni(bnatpya)Cl] (1) and [Ni(bnatpya)Cl] (2). The first single-molecule conductance measurements of a linear undeca-nickel chain were performed.

摘要

为了延长金属原子链的长度，用萘啶基部分对寡聚-α-吡啶氨基配体进行调节，得到了十一镍混合价配合物[Ni(bnatpya)Cl] (1)和[Ni(bnatpya)Cl] (2)。首次对线性十一镍链进行了单分子电导测量。

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