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Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate Fe complex with a NO coordination sphere.

作者信息

Murata Suguru, Takahashi Kazuyuki, Mochida Tomoyuki, Sakurai Takahiro, Ohta Hitoshi, Yamamoto Takashi, Einaga Yasuaki

机构信息

Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe, Hyogo 657-8501, Japan.

出版信息

Dalton Trans. 2017 May 9;46(18):5786-5789. doi: 10.1039/c7dt01030c.

DOI:10.1039/c7dt01030c
PMID:28406513
Abstract

A novel neutral heteroleptic Fe complex from two kinds of π-extended tridentate ligands was designed and prepared. The π-ligands formed a three-dimensional purely π-stacking interaction network. The present complex proved to be the first neutral spin-crossover (SCO) Fe complex with a NO coordination sphere exhibiting an abrupt SCO transition with a thermal hysteresis of 10 K and the light-induced excited spin-state trapping effect.

摘要

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