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利用金属-有机骨架从空气中收集水,并利用自然光提供动力。

Water harvesting from air with metal-organic frameworks powered by natural sunlight.

机构信息

Department of Mechanical Engineering, Massachusetts Institute of Technology (MIT), 77 Massachusetts Avenue, Cambridge, MA 02139, USA.

Department of Chemistry, Kavli Energy NanoScience Institute, and Berkeley Global Science Institute, University of California-Berkeley, Berkeley, CA 94720, USA.

出版信息

Science. 2017 Apr 28;356(6336):430-434. doi: 10.1126/science.aam8743. Epub 2017 Apr 13.

Abstract

Atmospheric water is a resource equivalent to ~10% of all fresh water in lakes on Earth. However, an efficient process for capturing and delivering water from air, especially at low humidity levels (down to 20%), has not been developed. We report the design and demonstration of a device based on a porous metal-organic framework {MOF-801, [ZrO(OH)(fumarate)]} that captures water from the atmosphere at ambient conditions by using low-grade heat from natural sunlight at a flux of less than 1 sun (1 kilowatt per square meter). This device is capable of harvesting 2.8 liters of water per kilogram of MOF daily at relative humidity levels as low as 20% and requires no additional input of energy.

摘要

大气水是一种资源,相当于地球上湖泊中所有淡水的 10%左右。然而,一种从空气中高效捕获和输送水的方法,特别是在低湿度水平(低至 20%)下,尚未开发出来。我们报告了一种基于多孔金属有机骨架{MOF-801,[ZrO(OH)(富马酸盐)]}的装置的设计和演示,该装置利用自然阳光中的低品位热能,在低于 1 个太阳(每平方米 1 千瓦)的通量下,在环境条件下从大气中捕获水。该装置能够以低至 20%的相对湿度水平,每天每公斤 MOF 收获 2.8 升水,并且不需要额外的能量输入。

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