Naderi Arman, Delavar Mohammad Amir, Kaboudin Babak, Askari Mohammad Sadegh
Department of Soil Science, Faculty of Agriculture, University of Zanjan, Zanjan, Iran.
Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Gavazang, Zanjan, Iran.
Environ Monit Assess. 2017 May;189(5):214. doi: 10.1007/s10661-017-5821-x. Epub 2017 Apr 13.
This study aims to assess and compare heavy metal distribution models developed using stepwise multiple linear regression (MSLR) and neural network-genetic algorithm model (ANN-GA) based on satellite imagery. The source identification of heavy metals was also explored using local Moran index. Soil samples (n = 300) were collected based on a grid and pH, organic matter, clay, iron oxide contents cadmium (Cd), lead (Pb) and zinc (Zn) concentrations were determined for each sample. Visible/near-infrared reflectance (VNIR) within the electromagnetic ranges of satellite imagery was applied to estimate heavy metal concentrations in the soil using MSLR and ANN-GA models. The models were evaluated and ANN-GA model demonstrated higher accuracy, and the autocorrelation results showed higher significant clusters of heavy metals around the industrial zone. The higher concentration of Cd, Pb and Zn was noted under industrial lands and irrigation farming in comparison to barren and dryland farming. Accumulation of industrial wastes in roads and streams was identified as main sources of pollution, and the concentration of soil heavy metals was reduced by increasing the distance from these sources. In comparison to MLSR, ANN-GA provided a more accurate indirect assessment of heavy metal concentrations in highly polluted soils. The clustering analysis provided reliable information about the spatial distribution of soil heavy metals and their sources.
本研究旨在评估和比较基于卫星图像,使用逐步多元线性回归(MSLR)和神经网络 - 遗传算法模型(ANN - GA)开发的重金属分布模型。还使用局部莫兰指数探索了重金属的来源识别。基于网格收集了土壤样本(n = 300),并测定了每个样本的pH值、有机质、粘土、氧化铁含量以及镉(Cd)、铅(Pb)和锌(Zn)的浓度。利用卫星图像电磁范围内的可见/近红外反射率(VNIR),通过MSLR和ANN - GA模型估算土壤中的重金属浓度。对模型进行了评估,ANN - GA模型显示出更高的准确性,自相关结果表明工业区周围重金属存在高度显著的聚类。与荒地和旱地农业相比,工业用地和灌溉农业下的Cd、Pb和Zn浓度更高。道路和溪流中工业废物的积累被确定为主要污染源,土壤重金属浓度随着与这些污染源距离的增加而降低。与MSLR相比,ANN - GA对高污染土壤中的重金属浓度提供了更准确的间接评估。聚类分析提供了有关土壤重金属空间分布及其来源的可靠信息。