• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

二水合双（4-氰基吡啶-κ）双（硫氰酸根合-κ）铁（II）4-氰基吡啶二溶剂合物的晶体结构

Crystal structure of di-aqua-bis-(4-cyano-pyridine-κ)bis-(thio-cyanato-κ)iron(II) 4-cyano-pyridine disolvate.

作者信息

Jochim Aleksej, Jess Inke, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Mar 3;73(Pt 4):463-466. doi: 10.1107/S205698901700322X. eCollection 2017 Apr 1.

DOI:10.1107/S205698901700322X
PMID:28435698
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5382599/
Abstract

The asymmetric unit of the title compound, [Fe(NCS)(CHN)(HO)]·2CHN, comprises one Fe cation occupying an inversion centre as well as one thio-cyanate anion, one water mol-ecule and two 4-cyano-pyridine mol-ecules in general positions. The iron cations are coordinated by two N-bonded thiocyanate anions, two (pyridine)N-bonded 4-cyano-pyridine ligands and two water mol-ecules into discrete complexes. The resulting coordination polyhedron can be described as a slightly distorted octa-hedron. The discrete complexes are connected through centrosymmetric pairs of (pyridine)C-H⋯N(cyano) hydrogen bonds into chains that are further linked into a three-dimensional network through inter-molecular O-H⋯N hydrogen bonds involving the 4-cyano-pyridine solvent mol-ecules.

摘要

标题化合物[Fe(NCS)(CHN)(HO)]·2CHN的不对称单元包含一个位于对称中心的铁阳离子，以及一个硫氰酸根阴离子、一个水分子和两个处于一般位置的4-氰基吡啶分子。铁阳离子由两个通过氮原子键合的硫氰酸根阴离子、两个通过（吡啶）氮原子键合的4-氰基吡啶配体和两个水分子配位形成离散的配合物。由此产生的配位多面体可描述为一个略有扭曲的八面体。离散的配合物通过（吡啶）C-H⋯N（氰基）氢键的中心对称对连接成链，这些链通过涉及4-氰基吡啶溶剂分子的分子间O-H⋯N氢键进一步连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/0675fb0696c9/e-73-00463-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/29e50608c45a/e-73-00463-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/a8ef6851efd4/e-73-00463-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/0675fb0696c9/e-73-00463-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/29e50608c45a/e-73-00463-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/a8ef6851efd4/e-73-00463-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/50b5/5382599/0675fb0696c9/e-73-00463-fig3.jpg

相似文献

1
Crystal structure of di-aqua-bis-(4-cyano-pyridine-κ)bis-(thio-cyanato-κ)iron(II) 4-cyano-pyridine disolvate.二水合双（4-氰基吡啶-κ）双（硫氰酸根合-κ）铁（II）4-氰基吡啶二溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Mar 3;73(Pt 4):463-466. doi: 10.1107/S205698901700322X. eCollection 2017 Apr 1.
2
Synthesis, crystal structure and properties of tetra-kis-(pyridine-3-carbo-nitrile)-dithio-cyanatoiron(II) and of diaqua-bis-(pyridine-3-carbo-nitrile)-di-thio-cyanatoiron(II) pyridine-3-carbo-nitrile monosolvate.四 - （吡啶 - 3 - 甲腈） - 二硫氰酸根合铁（II）以及二水合双 - （吡啶 - 3 - 甲腈） - 二硫氰酸根合铁（II）吡啶 - 3 - 甲腈单溶剂合物的合成、晶体结构与性质
Acta Crystallogr E Crystallogr Commun. 2023 Oct 31;79(Pt 11):1093-1099. doi: 10.1107/S205698902300909X. eCollection 2023 Nov 1.
3
Crystal structures of two Co(NCS) urotropine coordination compounds with different Co coordinations.两种具有不同钴配位方式的硫氰酸钴乌洛托品配位化合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2022 Feb 3;78(Pt 3):264-269. doi: 10.1107/S2056989022001037. eCollection 2022 Feb 1.
4
Crystal structures of tetra-kis-(pyridine-4-thio-amide-κ)bis-(thio-cyanato-κ)cobalt(II) monohydrate and bis-(pyridine-4-thio-amide-κ)bis-(thio-cyanato-κ)zinc(II).四 - （吡啶 - 4 - 硫代酰胺 - κ）双 - （硫氰酸根合 - κ）钴（II）一水合物和双 - （吡啶 - 4 - 硫代酰胺 - κ）双 - （硫氰酸根合 - κ）锌（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Jan 12;74(Pt 2):141-146. doi: 10.1107/S205698901800021X. eCollection 2018 Feb 1.
5
Crystal structure of bis-(4-acetyl-pyridine-κN)bis-(ethanol-κO)bis-(thio-cyanato-κN)manganese(II).双（4-乙酰基吡啶-κN）双（乙醇-κO）双（硫氰酸根合-κN）锰（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Mar 11;71(Pt 4):m81-2. doi: 10.1107/S2056989015004533. eCollection 2015 Apr 1.
6
Crystal structure of aqua-tris-(isonicotinamide-κ)bis-(thio-cyanato-κ)cobalt(II) 2.5-hydrate.水合三（异烟酰胺-κ）二（硫氰酸根-κ）钴（II）2.5水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Aug 9;72(Pt 9):1263-1266. doi: 10.1107/S2056989016012470. eCollection 2016 Sep 1.
7
Crystal structures of (aceto-nitrile-κ)tris-(pyridine-4-thio-amide-κ)bis-(thio-cyanate-κ)cobalt(II) aceto-nitrile disolvate and tetra-kis-(pyridine-4-thio-amide-κ)bis-(thio-cyanate-κ)nickel(II) methanol penta-solvate.（乙腈-κ）三（4-吡啶硫代酰胺-κ）双（硫氰酸根-κ）钴（II）乙腈二溶剂合物和四（4-吡啶硫代酰胺-κ）双（硫氰酸根-κ）镍（II）甲醇五溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Jun 12;74(Pt 7):964-969. doi: 10.1107/S2056989018007612. eCollection 2018 Jul 1.
8
Crystal structure of di-aqua-bis-(2,6-di-methyl-pyrazine-κN (4))bis-(thio-cyanato-κN)cobalt(II) 2,5-di-methyl-pyrazine monosolvate.二水双（2,6-二甲基吡嗪-κN(4)）双（硫氰酸根-κN）钴（II）2,5-二甲基吡嗪单溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Dec 6;71(Pt 12):m242-3. doi: 10.1107/S2056989015021829. eCollection 2015 Dec 1.
9
Crystal structure of di-aqua-bis-(2-chloro-pyridine-κ)bis-(thio-cyanato-κ)nickel(II).二水合双（2-氯吡啶-κ）双（硫氰酸根-κ）镍（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Sep 30;72(Pt 10):1492-1494. doi: 10.1107/S2056989016015218. eCollection 2016 Oct 1.
10
Crystal structure of catena-poly[[[bis-(pyridine-4-carbo-thio-amide-κN (1))cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N] methanol disolvate].链状聚[[[双-(吡啶-4-碳硫酰胺-κN(1))镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]]甲醇溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Feb 20;72(Pt 3):370-3. doi: 10.1107/S2056989016002632. eCollection 2016 Mar 1.

本文引用的文献

1
Influence of metal coordination and co-ligands on the magnetic properties of 1D Co(NCS) coordination polymers.金属配位及共配体对一维Co(NCS)配位聚合物磁性的影响
Phys Chem Chem Phys. 2017 Jan 25;19(4):3232-3243. doi: 10.1039/c6cp08193b.
2
Synthesis, structures, magnetic, and theoretical investigations of layered Co and Ni thiocyanate coordination polymers.层状钴和镍硫氰酸盐配位聚合物的合成、结构、磁性及理论研究
Dalton Trans. 2016 Nov 15;45(45):18190-18201. doi: 10.1039/c6dt03752f.
3
The Cambridge Structural Database.剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
4
Metamagnetism and single-chain magnetic behavior in a homospin one-dimensional iron(II) coordination polymer.同自旋一维铁(II)配位聚合物中的反铁磁性和单链磁性行为。
Chemistry. 2012 Apr 23;18(17):5284-9. doi: 10.1002/chem.201103416. Epub 2012 Mar 20.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
6
New 1- and 2-dimensional polymeric structures of cyanopyridine complexes of Ag(I) and Cu(I).银（I）和铜（I）的氰基吡啶配合物的新型一维和二维聚合物结构。
Inorg Chem. 2004 Jan 12;43(1):181-8. doi: 10.1021/ic030254w.