Kazin Pavel E, Zykin Mikhail A, Trusov Lev A, Eliseev Artem A, Magdysyuk Oxana V, Dinnebier Robert E, Kremer Reinhard K, Felser Claudia, Jansen Martin
Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.
Department of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russia.
Chem Commun (Camb). 2017 May 11;53(39):5416-5419. doi: 10.1039/c7cc02453c.
An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier U of up to 387 cm, which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).
一种在三角通道中钴离子含量高的磷灰石型磷酸钡具有缓慢的磁化弛豫，其能垒U高达387厘米，这远高于迄今为止所有已知的基于d金属的单分子磁体（SMM）的值。
