Department of Environment Studies, Panjab University, Chandigarh 160014, India.
Department of Environment Studies, Panjab University, Chandigarh 160014, India.
Chemosphere. 2017 Sep;182:129-136. doi: 10.1016/j.chemosphere.2017.05.026. Epub 2017 May 4.
In a screenhouse experiment, we investigated the role of two environment friendly chelants, Ammonium molybdate and EDDS for Pb mobilisation and its extraction by Coronopus didymus under completely randomized controlled conditions. Seedlings of C. didymus were grown in pots having Pb-contaminated soil (1200 and 2200 mg kg) for 6 weeks. Plants were harvested, 1 week after the addition of A. molybdate and EDDS. Results revealed that A. molybdate and EDDS enhanced the uptake and accumulation of Pb in roots and shoots of C. didymus. At 2200 mg kg Pb level, compared to Pb-alone treatment, the maximal concentration of Pb was increased upto ∼10% and ∼19%, in roots whereas ∼8% and ∼18%, respectively, in shoots on addition of 2 mmol kg A. molybdate and EDDS. Additionally, Pb + EDDS treatments enhanced the plant biomass and triggered strong antioxidative response, more efficaciously than Pb + A. molybdate and Pb-alone treated plants. In this study, EDDS relative to A. molybdate was more efficient in mobilising and extracting Pb from soil. Although, EDDS followed by A. molybdate had good efficacy in mitigating Pb from contaminated soils but C. didymus itself has the inherent affinity to tolerate and accumulate Pb from contaminated soils and hence in future, can be used either alone or with some other eco-friendly amendments for soil remediation purposes.
在一个遮雨棚实验中,我们研究了两种环保螯合剂——钼酸铵和 EDDS——在完全随机对照条件下对 Pb 活化及其由冠状毛茛(Coronopus didymus)提取的作用。将冠状毛茛的幼苗种植在含有 Pb 污染土壤(1200 和 2200 mg/kg)的盆中 6 周。在添加 A. molybdate 和 EDDS 1 周后,收获植物。结果表明,A. molybdate 和 EDDS 增强了 Pb 在冠状毛茛根部和地上部分的吸收和积累。在 2200 mg/kg Pb 水平下,与单独的 Pb 处理相比,添加 2 mmol/kg A. molybdate 和 EDDS 后,Pb 的最大浓度在根部增加了约 10%和 19%,在地上部分分别增加了约 8%和 18%。此外,Pb+EDDS 处理增强了植物生物量,并引发了强烈的抗氧化反应,比 Pb+A. molybdate 和单独的 Pb 处理植物更有效。在这项研究中,EDDS 比 A. molybdate 更有效地从土壤中活化和提取 Pb。尽管 EDDS 随后添加 A. molybdate 对减轻污染土壤中的 Pb 具有良好的效果,但冠状毛茛本身具有耐受和从污染土壤中积累 Pb 的内在亲和力,因此在未来,可以单独使用或与其他一些环保改良剂一起用于土壤修复目的。