离子烯水溶液的体积和量热性质。
Volumetric and calorimetric properties of aqueous ionene solutions.
作者信息
Lukšič Miha, Hribar-Lee Barbara
机构信息
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, SI-1000 Ljubljana, Slovenia.
出版信息
J Mol Liq. 2017 Feb;228:126-132. doi: 10.1016/j.molliq.2016.09.043. Epub 2016 Sep 23.
Abstract
The volumetric (partial and apparent molar volumes) and calorimetric properties (apparent heat capacities) of aqueous cationic polyelectrolyte solutions - ionenes - were studied using the oscillating tube densitometer and differential scanning calorimeter. The polyion's charge density and the counterion properties were considered as variables. The special attention was put to evaluate the contribution of electrostatic and hydrophobic effects to the properties studied. The contribution of the CH group of the polyion's backbone to molar volumes and heat capacities was estimated. Synergistic effect between polyion and counterions was found.
摘要
使用振荡管密度计和差示扫描量热仪研究了阳离子聚电解质水溶液（紫罗碱）的体积性质（偏摩尔体积和表观摩尔体积）和量热性质（表观热容）。将聚离子的电荷密度和抗衡离子性质视为变量。特别关注评估静电和疏水作用对所研究性质的贡献。估算了聚离子主链中-CH基团对摩尔体积和热容的贡献。发现了聚离子与抗衡离子之间的协同效应。
相似文献
1
Volumetric and calorimetric properties of aqueous ionene solutions.离子烯水溶液的体积和量热性质。
J Mol Liq. 2017 Feb;228:126-132. doi: 10.1016/j.molliq.2016.09.043. Epub 2016 Sep 23.
2
On the crossroads of current polyelectrolyte theory and counterion-specific effects.处于当前聚电解质理论与反离子特异性效应的交叉点上。
Phys Chem Chem Phys. 2015 Feb 28;17(8):5650-8. doi: 10.1039/c4cp05469e.
3
Aqueous solutions of ionenes: interactions and counterion specific effects as seen by neutron scattering.离子聚合物的水溶液：通过中子散射观察到的相互作用和抗衡离子特异性效应。
Phys Chem Chem Phys. 2012 Oct 5;14(37):12898-904. doi: 10.1039/c2cp41859b.
4
Interplay of ion-specific and charge-density effects in aqueous solutions of weakly charged ionenes as revealed by electric-transport measurements.离子特异性和电荷密度效应对弱荷电离子聚合物水溶液中电输运的影响。
J Phys Chem B. 2010 Aug 19;114(32):10401-8. doi: 10.1021/jp105301m.
5
Isothermal titration calorimetry and molecular dynamics study of ion-selectivity in mixtures of hydrophobic polyelectrolytes with sodium halides in water.水相中疏水性聚电解质与卤化钠混合物中离子选择性的等温热力学滴定法和分子动力学研究。
Phys Chem Chem Phys. 2012 Feb 14;14(6):2024-31. doi: 10.1039/c2cp23137a. Epub 2012 Jan 9.
6
Presence of hydrophobic groups may modify the specific ion effect in aqueous polyelectrolyte solutions.疏水性基团的存在可能会改变水相聚电解质溶液中的特殊离子效应。
J Phys Chem B. 2013 Apr 4;117(13):3682-8. doi: 10.1021/jp401313f. Epub 2013 Mar 26.
7
Ion-chromatographic selectivity of polyelectrolyte sorbents based on some aliphatic and aromatic ionenes.基于某些脂肪族和芳香族紫罗碱的聚电解质吸附剂的离子色谱选择性
J Chromatogr A. 2000 Jul 7;884(1-2):31-9. doi: 10.1016/s0021-9673(00)00273-9.
8
Explicit water molecular dynamics study of the mobility of halide ions in presence of ionene oligocations.离子液体中寡聚离子对卤离子迁移率的分子动力学研究
J Chem Phys. 2012 Jul 7;137(1):014511. doi: 10.1063/1.4731718.
9
Modelling fast mode dielectric relaxation of counterions in aqueous solutions of ionene bromides and fluorides.模拟离子液体溴化物和氟化物水溶液中抗衡离子的快速模式介电弛豫。
Phys Chem Chem Phys. 2009 Nov 21;11(43):10053-8. doi: 10.1039/b914938b. Epub 2009 Sep 11.
10
Specific counter-ion and co-ion effects revealed in mixing of aqueous solutions of 3,3 and 6,6-ionenes with solutions of low molecular weight salts.在 3,3 和 6,6-聚离子与低分子量盐溶液混合时表现出的特定抗衡离子和共离子效应。
Phys Chem Chem Phys. 2012 May 21;14(19):6805-11. doi: 10.1039/c2cp40571g. Epub 2012 Apr 10.
引用本文的文献
1
DNA-Polyelectrolyte Complexation Study: The Effect of Polyion Charge Density and Chemical Nature of the Counterions.DNA-聚电解质络合研究：聚离子电荷密度和抗衡离子化学性质的影响。
J Phys Chem B. 2018 May 31;122(21):5381-5388. doi: 10.1021/acs.jpcb.7b11094. Epub 2018 Feb 5.
本文引用的文献
1
On the crossroads of current polyelectrolyte theory and counterion-specific effects.处于当前聚电解质理论与反离子特异性效应的交叉点上。
Phys Chem Chem Phys. 2015 Feb 28;17(8):5650-8. doi: 10.1039/c4cp05469e.
2
Tuning the Hydrophobic Interaction: Ultrafast Optical Kerr Effect Study of Aqueous Ionene Solutions.调节疏水相互作用：离子烯水溶液的超快光学克尔效应研究
J Phys Chem B. 2015 Jul 23;119(29):8900-8. doi: 10.1021/jp506701a. Epub 2014 Nov 3.
3
Presence of hydrophobic groups may modify the specific ion effect in aqueous polyelectrolyte solutions.疏水性基团的存在可能会改变水相聚电解质溶液中的特殊离子效应。
J Phys Chem B. 2013 Apr 4;117(13):3682-8. doi: 10.1021/jp401313f. Epub 2013 Mar 26.
4
Aqueous solutions of ionenes: interactions and counterion specific effects as seen by neutron scattering.离子聚合物的水溶液：通过中子散射观察到的相互作用和抗衡离子特异性效应。
Phys Chem Chem Phys. 2012 Oct 5;14(37):12898-904. doi: 10.1039/c2cp41859b.
5
Specific counter-ion and co-ion effects revealed in mixing of aqueous solutions of 3,3 and 6,6-ionenes with solutions of low molecular weight salts.在 3,3 和 6,6-聚离子与低分子量盐溶液混合时表现出的特定抗衡离子和共离子效应。
Phys Chem Chem Phys. 2012 May 21;14(19):6805-11. doi: 10.1039/c2cp40571g. Epub 2012 Apr 10.
6
Signature of hydrophobic hydration in a single polymer.单一聚合物中疏水性水合作用的特征。
Proc Natl Acad Sci U S A. 2011 Oct 4;108(40):16527-32. doi: 10.1073/pnas.1105450108. Epub 2011 Sep 12.
7
Self-assembly of an optically active conjugated oligoelectrolyte.手性共轭寡聚电解质的自组装。
J Am Chem Soc. 2011 Jun 1;133(21):8380-7. doi: 10.1021/ja202776b. Epub 2011 May 6.
8
Interplay of ion-specific and charge-density effects in aqueous solutions of weakly charged ionenes as revealed by electric-transport measurements.离子特异性和电荷密度效应对弱荷电离子聚合物水溶液中电输运的影响。
J Phys Chem B. 2010 Aug 19;114(32):10401-8. doi: 10.1021/jp105301m.
9
Emerging applications of stimuli-responsive polymer materials.刺激响应型聚合物材料的新兴应用。
Nat Mater. 2010 Feb;9(2):101-13. doi: 10.1038/nmat2614. Epub 2010 Jan 22.
10
Modelling fast mode dielectric relaxation of counterions in aqueous solutions of ionene bromides and fluorides.模拟离子液体溴化物和氟化物水溶液中抗衡离子的快速模式介电弛豫。
Phys Chem Chem Phys. 2009 Nov 21;11(43):10053-8. doi: 10.1039/b914938b. Epub 2009 Sep 11.
Zotero 插件