Cai Zhen-Wen, Yang Tao, Qi Yan-Jie, Li Xin-Xiong, Zheng Shou-Tian
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
Dalton Trans. 2017 May 30;46(21):6848-6852. doi: 10.1039/c7dt00892a.
We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {SbScW}, {SbScW}, and {SbScW}. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc ions of any polyoxotungstates reported to date.
我们报道了一系列新型的含钪纳米级六聚多金属氧酸盐{SbScW}、{SbScW}和{SbScW}的温度分辨组装。这些化合物包括最大的含钪聚钨酸盐,并且是迄今为止报道的所有聚钨酸盐中含钪离子数量最多的。