膦催化萘酚与对亚甲基苯醌的傅克反应：便捷合成三芳基甲烷的方法
Phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes.
作者信息
Zhou Tao, Li Shenhuan, Huang Ben, Li Cao, Zhao Yang, Chen Jieqiong, Chen Aoling, Xiao Yuanjin, Liu Lu, Zhang Junliang
机构信息
School of Chemistry and Molecular Engineering, East China Normal University, 500 Dongchuan Road, Shanghai 200241, China.
出版信息
Org Biomol Chem. 2017 Jun 14;15(23):4941-4945. doi: 10.1039/c7ob00911a.
PMID:28509922
Abstract
We developed a novel phosphine-catalyzed Friedel-Crafts reaction of naphthols with para-quinone methides (p-QMs). This reaction provided a promising method for the synthesis of triarylmethanes, which widely exist in natural products and in molecules which have been shown to have biological and pharmacological activity.
摘要
我们开发了一种新型的萘酚与对醌甲基化物（p-QMs）的膦催化傅克反应。该反应为合成三芳基甲烷提供了一种有前景的方法，三芳基甲烷广泛存在于天然产物以及已显示具有生物和药理活性的分子中。
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