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基于 Pt/NbO 纳米带的高稳定纳米结构膜电极组件,用于质子交换膜燃料电池,可减少铂载量。

Highly stable nanostructured membrane electrode assembly based on Pt/NbO nanobelts with reduced platinum loading for proton exchange membrane fuel cells.

机构信息

Fuel Cell System and Engineering Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China.

出版信息

Nanoscale. 2017 May 25;9(20):6910-6919. doi: 10.1039/c7nr01491k.

Abstract

Proton exchange membrane fuel cells are promising candidates for the next-generation power sources; however, poor durability and high cost impede their widespread application. To address this dilemma, a nanostructured membrane electrode assembly (MEA) based on Pt/NbO nanobelts (NBs) was constructed through hydrothermal synthesis and the physical vapour deposition method. Pt/NbO NBs were directly aligned with Nafion membrane without ionomer as a binder. The prepared catalyst layer is ultrathin and has ultralow Pt loading. A single cell performance of 5.80 kW g (cathode) and 12.03 kW g (anode) was achieved by the Pt/NbO NBs-based MEA (66.0 μg cm). The accelerated durability test indicates that the Pt/NbO NBs-based MEA is far more stable than conventional Pt/C-based MEA.

摘要

质子交换膜燃料电池有望成为下一代能源的候选者;然而,较差的耐久性和高成本阻碍了它们的广泛应用。为了解决这一困境,通过水热合成和物理气相沉积法构建了基于 Pt/NbO 纳米带 (NBs) 的纳米结构膜电极组件 (MEA)。Pt/NbO NBs 直接与 Nafion 膜对齐,没有离聚物作为粘结剂。所制备的催化剂层非常薄,Pt 负载量超低。基于 Pt/NbO NBs 的 MEA(66.0μg cm)实现了 5.80 kW g(阴极)和 12.03 kW g(阳极)的单电池性能。加速耐久性测试表明,基于 Pt/NbO NBs 的 MEA 比传统的 Pt/C 基 MEA 稳定得多。

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