Yu Liu-Zhu, Chen Kai, Zhu Zi-Zhong, Shi Min
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China.
Chem Commun (Camb). 2017 May 30;53(44):5935-5945. doi: 10.1039/c7cc02596c.
During the past several years, functionalized alkylidenecyclopropanes (FACPs) have attracted intensive attention in synthetic chemistry. Many interesting transformations of FACPs have been developed to synthesize a lot of structurally diverse and valuable polycyclic and heterocyclic compounds. This review will classify FACPs into aryl-FACPs, alkyl-FACPs and ring-FACPs for the first time, and recent interesting chemical transformations in these research fields will be included, respectively, from 2011. Moreover, we will pay more attention to the clarification of the reaction mechanism, in which the C-C bond cleavage of alkylidenecyclopropanes (ACPs) will be emphasized.
在过去几年中，官能化亚烷基环丙烷（FACPs）在合成化学领域引起了广泛关注。人们已经开发出许多有趣的FACPs转化反应，用于合成大量结构多样且有价值的多环和杂环化合物。本综述将首次将FACPs分为芳基-FACPs、烷基-FACPs和环-FACPs，并分别涵盖自2011年以来这些研究领域中最近有趣的化学转化反应。此外，我们将更加关注反应机理的阐明，其中将重点强调亚烷基环丙烷（ACPs）的C-C键断裂。
