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通过与导电聚合物进行受控电子转移对铁/铁层状双氢氧化物(“绿色锈”)进行的一种新型合成方法。

A novel synthesis of an Fe/Fe layered double hydroxide ('green rust') via controlled electron transfer with a conducting polymer.

作者信息

Kim Min-Sung, Kim Tae-Hyun, Seo Young Sun, Oh Jae-Min, Park Jin Kuen

机构信息

Department of Chemistry, Hankuk University of Foreign Studies, Yongin 17035, Republic of Korea.

Department of Chemistry and Medical Chemistry, College of Science and Technology, Yonsei University, Wonju 26493, Republic of Korea.

出版信息

Dalton Trans. 2017 Jun 28;46(24):7656-7659. doi: 10.1039/c7dt00731k. Epub 2017 May 17.

DOI:10.1039/c7dt00731k
PMID:28513679
Abstract

This report examines the influence of a conducting polymer on the crystal growth of labile green rust (GR) through hybridization with polypyrrole. All hybrids used in this study were prepared via one-pot co-precipitation at neutral pH, with specific stoichiometric ratios among all chemical species. The role of the conducting polymer and the effective stoichiometric ratio were demonstrated to facilitate the crystal growth of GR.

摘要

本报告研究了导电聚合物通过与聚吡咯杂交对不稳定绿锈(GR)晶体生长的影响。本研究中使用的所有杂化物均在中性pH值下通过一锅共沉淀法制备,所有化学物质之间具有特定的化学计量比。结果表明,导电聚合物的作用和有效的化学计量比促进了GR的晶体生长。

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