Dipartimento di Chimica, Università di Roma Sapienza, Rome, Italy.
Dipartimento di Fisica e Chimica, Università di Palermo, Palermo, Italy.
Top Curr Chem (Cham). 2017 Jun;375(3):58. doi: 10.1007/s41061-017-0147-2. Epub 2017 May 17.
We discuss some published results and provide new observations concerning the high level of structural complexity that lies behind the nanoscale correlations in ionic liquids (ILs) and their mixtures with molecular liquids. It turns out that this organization is a consequence of the hierarchical construction on both spatial (from ångström to several nanometer) and temporal (from fraction of picosecond to hundreds of nanosecond) scales, which requires joint use of experimental and computational tools.
我们讨论了一些已发表的结果,并提供了关于离子液体 (ILs) 及其与分子液体混合物中纳米级相关性背后的高水平结构复杂性的新观察结果。事实证明,这种组织是空间(从埃到几个纳米)和时间(从飞秒到数百纳秒的分数)尺度上的层次结构的结果,这需要实验和计算工具的联合使用。