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聚丙烯酰胺和聚(N,N-二甲基丙烯酰胺)接枝纤维素纳米晶作为高岭土悬浮液的有效絮凝剂。

Polyacrylamide and poly(N,N-dimethylacrylamide) grafted cellulose nanocrystals as efficient flocculants for kaolin suspension.

机构信息

College of Material Science and Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China.

出版信息

Int J Biol Macromol. 2017 Oct;103:1107-1112. doi: 10.1016/j.ijbiomac.2017.05.098. Epub 2017 May 19.

Abstract

Natural polymer flocculants for wastewater treatment have received close attention in recent years. Here we used two flocculants, polyacrylamide and poly(N,N-dimethylacrylamide) grafted cellulose nanocrystals synthesized by a "macro-RAFT assisted" strategy, for the flocculation of kaolin suspension. The flocculation performance of these two flocculants, including flocculants dosage, settling time and floc size, was carefully studied and compared. Results suggested that poly(N,N-dimethylacrylamide) grafted cellulose nanocrstyals showed better flocculation performance than polyacrylamide grafted ones. Meanwhile, their flocculation behavior was also compared with other cellulose-based flocculants in literature and we suggested polymer modified cellulose nanocrstals as flocculants might have higher flocculation performance, but this needs further verification.

摘要

近年来,用于废水处理的天然聚合物絮凝剂受到了密切关注。在这里,我们使用了两种絮凝剂,即用“大分子 RAFT 辅助”策略合成的聚丙烯酰胺和接枝纤维素纳米晶体的聚(N,N-二甲基丙烯酰胺),用于高岭土悬浮液的絮凝。仔细研究和比较了这两种絮凝剂的絮凝性能,包括絮凝剂用量、沉降时间和絮体大小。结果表明,接枝纤维素纳米晶体的聚(N,N-二甲基丙烯酰胺)比接枝聚丙烯酰胺的絮凝性能更好。同时,还将它们的絮凝行为与文献中的其他基于纤维素的絮凝剂进行了比较,并提出聚合物改性纤维素纳米晶体作为絮凝剂可能具有更高的絮凝性能,但这需要进一步验证。

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