二氯化双（二甲亚砜-κ）双（4-氟苄基-κ）锡（IV）：晶体结构与 Hirshfeld 表面分析
-Di-chlorido-bis-(dimethyl sulfoxide-κ)bis-(4-fluoro-benzyl-κ)tin(IV): crystal structure and Hirshfeld surface analysis.
作者信息
Amin Nur Adibah Binti Mohd, Hussen Rusnah Syahila Duali, Lee See Mun, Halcovitch Nathan R, Jotani Mukesh M, Tiekink Edward R T
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Apr 7;73(Pt 5):667-672. doi: 10.1107/S2056989017005072. eCollection 2017 May 1.
The Sn atom in the title diorganotin compound, [Sn(CHF)Cl(CHOS)], is located on a centre of inversion, resulting in the CClO donor set having an all- disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.
在标题二有机锡化合物[Sn(CHF)Cl(CHOS)]中，Sn原子位于一个反演中心上，使得CClO供体组具有同类原子的全错位排列。配位几何形状近似八面体。该晶体具有C—H⋯F、C—H⋯Cl和C—H⋯π相互作用，形成了一个三维网络。通过对Hirshfeld表面的分析，可以清楚地看出Cl⋯H/H⋯Cl和F⋯H/H⋯F接触对分子堆积的各自影响。
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