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两种碱土金属（钡和锶）二价锰（II）三价铁（III）三（正磷酸盐）的晶体结构

Crystal structures of two alkaline earth ( = Ba and Sr) dimanganese(II) iron(III) tris-(orthophosphates).

作者信息

Alhakmi Ghaleb, Assani Abderrazzak, Saadi Mohamed, El Ammari Lahcen

机构信息

Laboratoire de Chimie du Solide Appliquée, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Battouta, BP 1014, Rabat, Morocco.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Apr 28;73(Pt 5):767-770. doi: 10.1107/S2056989017006120. eCollection 2017 May 1.

DOI:10.1107/S2056989017006120
PMID:28529794
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5418802/
Abstract

Two new orthophosphates, BaMnFe(PO) [barium dimanganese(II) iron(III) tris-(orthophosphate)] and SrMnFe(PO) [strontium dimanganese(II) iron(III) tris-(orthophosphate)], were synthesized by solid-state reactions. They are isotypic and crystallize in the ortho-rhom-bic system with space group type . Their crystal structures comprise infinite zigzag chains of edge-sharing FeO octa-hedra (point group symmetry .2.) and MnO double octa-hedra running parallel to [001], linked by two types of PO tetra-hedra. The so-formed three-dimensional framework delineates channels running along [001], in which the alkaline earth cations (site symmetry .2.) are located within a neighbourhood of eight O atoms.

摘要

通过固态反应合成了两种新型正磷酸盐，即BaMnFe(PO) [钡二锰(II)铁(III)三(正磷酸盐)]和SrMnFe(PO) [锶二锰(II)铁(III)三(正磷酸盐)]。它们是同型的，结晶于正交晶系，空间群类型为 。它们的晶体结构由沿[001]方向平行排列的无限之字形链组成，这些链由边共享的FeO八面体（点群对称性.2.）和MnO双八面体构成，通过两种类型的PO四面体相连。如此形成的三维骨架勾勒出沿[001]方向的通道，碱土金属阳离子（位点对称性.2.）位于八个O原子的邻域内。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/e0828099e6af/e-73-00767-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/2978e6aaecd5/e-73-00767-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/b6684375b929/e-73-00767-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/dd6e469217c9/e-73-00767-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/549fc5697582/e-73-00767-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/fee47caa2c0b/e-73-00767-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/e0828099e6af/e-73-00767-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/2978e6aaecd5/e-73-00767-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/b6684375b929/e-73-00767-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/dd6e469217c9/e-73-00767-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/549fc5697582/e-73-00767-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/fee47caa2c0b/e-73-00767-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb10/5418802/e0828099e6af/e-73-00767-fig6.jpg

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