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介电超表面修饰碳纳米管的单氧掺杂发光。

Solitary Oxygen Dopant Emission from Carbon Nanotubes Modified by Dielectric Metasurfaces.

机构信息

Center for Integrated Nanotechnologies, Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.

Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.

出版信息

ACS Nano. 2017 Jun 27;11(6):6431-6439. doi: 10.1021/acsnano.7b02951. Epub 2017 Jun 5.

Abstract

All-dielectric metasurfaces made from arrays of high index nanoresonators supporting strong magnetic dipole modes have emerged as a low-loss alternative to plasmonic metasurfaces. Here we use oxygen-doped single-walled carbon nanotubes (SWCNTs) as quantum emitters and couple them to silicon metasurfaces to study effects of the magnetic dipole modes of the constituent nanoresonators on the photoluminescence (PL) of individual SWCNTs. We find that when in resonance, the magnetic mode of the silicon nanoresonators can lead to a moderate average PL enhancement of 0.8-4.0 of the SWCNTs, accompanied by an average increase in the radiative decay rate by a factor of 1.5-3.0. More interestingly, single dopant polarization experiments show an anomalous photoluminescence polarization rotation by coupling individual SWCNTs to silicon nanoresonators. Numerical simulations indicate that this is caused by modification of near-field polarization distribution at certain areas in the proximity of the silicon nanoresonators at the excitation wavelength, thus presenting an approach to control emission polarization. These findings indicate silicon nanoresonators as potential building blocks of quantum photonic circuits capable of manipulating PL intensity and polarization of single photon sources.

摘要

由高折射率纳米谐振器阵列构成的全介质超表面因其低损耗的特性,成为等离子体超表面的替代品。在这里,我们使用掺氧单壁碳纳米管 (SWCNTs) 作为量子发射器,并将其与硅超表面耦合,以研究组成纳米谐振器的磁偶极子模式对单个 SWCNTs 光致发光 (PL) 的影响。我们发现,当处于共振状态时,硅纳米谐振器的磁模式可以使 SWCNTs 的平均 PL 增强 0.8-4.0,同时平均辐射衰减率增加 1.5-3.0 倍。更有趣的是,通过将单个掺杂剂与硅纳米谐振器耦合进行单掺杂极化实验,我们观察到异常的光致发光偏振旋转。数值模拟表明,这是由于在激发波长下硅纳米谐振器附近特定区域的近场偏振分布发生了变化,从而为控制发射偏振提供了一种方法。这些发现表明,硅纳米谐振器作为量子光子电路的潜在构建模块,能够操纵单光子源的 PL 强度和偏振。

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