Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu, India.
Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu, India.
Int J Biol Macromol. 2017 Nov;104(Pt B):1459-1468. doi: 10.1016/j.ijbiomac.2017.05.117. Epub 2017 May 24.
Removal of heavy metals from wastewater is essential to avoid water pollution. In the present study, the performance of Chitosan and Alginate nanocomposites was evaluated for the removal of chromium (VI) from water waste. The physicochemically characterized (FT-IR, XRD, SEM, DSC, and DLS) for wastewater treatment were studied. Batch adsorption experiments were performed to examine the removal process under various factors like the effects of initial concentration, adsorbent dose, pH, and agitation time. The metal ion removal was pH dependent and reached optimum at pH 5.0. Experimental data were analyzed by Langmuir and Freundlich adsorption isotherms. The isotherm study revealed that the adsorption equilibrium is well-fitted to the Freundlich isotherm and the sorption capacity of Chitosan and Alginate nanocomposites is very high, and the adsorbent favors multilayer adsorption. Pseudo-first- and -second-order kinetics models were used for describing kinetic data. It was determined that removal of Cr (VI) be well-fitted by second-order reaction kinetics. From the results, it was concluded that Chitosan and Alginate Nanocomposites is an excellent material as a biosorbent for Cr(VI) from water waste.
从废水中去除重金属对于避免水污染至关重要。在本研究中,评估了壳聚糖和藻酸盐纳米复合材料去除废水中六价铬的性能。对用于废水处理的纳米复合材料进行了物理化学特性表征(FT-IR、XRD、SEM、DSC 和 DLS)。进行了批量吸附实验,以研究各种因素(如初始浓度、吸附剂剂量、pH 值和搅拌时间)对去除过程的影响。金属离子去除与 pH 值有关,在 pH 值为 5.0 时达到最佳效果。通过 Langmuir 和 Freundlich 吸附等温线分析了实验数据。等温线研究表明,吸附平衡很好地符合 Freundlich 等温线,并且壳聚糖和藻酸盐纳米复合材料的吸附容量非常高,吸附剂有利于多层吸附。采用伪一级和二级动力学模型来描述动力学数据。结果表明,Cr(VI)的去除很好地符合二级反应动力学。从结果可以得出结论,壳聚糖和藻酸盐纳米复合材料是一种从废水中去除 Cr(VI)的优良生物吸附剂材料。