基于杯[6]芳烃的分子容器对气体的封装和固态隔离
Encapsulation and solid state sequestration of gases by calix[6]arene-based molecular containers.
作者信息
Lavendomme Roy, Ajami Daniela, Moerkerke Steven, Wouters Johan, Rissanen Kari, Luhmer Michel, Jabin Ivan
机构信息
Laboratoire de Chimie Organique, Université libre de Bruxelles (ULB), Avenue F.D. Roosevelt 50, CP160/06, B-1050 Brussels, Belgium.
出版信息
Chem Commun (Camb). 2017 Jun 13;53(48):6468-6471. doi: 10.1039/c7cc03078a.
Two calix[6]arene-based molecular containers were synthesized in high yields. These containers can encapsulate small guests through a unique "rotating door" complexation process. The sequestration of greenhouse gases is clearly demonstrated. They can be stored in the solid state for long periods and released via dissolution of the inclusion complex.
以高产率合成了两种基于杯[6]芳烃的分子容器。这些容器可以通过独特的“旋转门”络合过程封装小客体。温室气体的螯合作用得到了明确证明。它们可以长期以固态储存，并通过包合物的溶解释放出来。
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