School of Mathematical Sciences, Peking University, Beijing 100871, P. R. China.
LMAM, CAPT and School of Mathematical Sciences, Peking University, Beijing 100871, P. R. China.
Soft Matter. 2017 Jul 14;13(26):4607-4615. doi: 10.1039/c7sm00354d. Epub 2017 Jun 12.
The structure and phase behaviour of bilayer membranes self-assembled from rod-coil diblock copolymers are studied using the self-consistent field theory, focusing on the occurrence and relative stability of liquid crystalline phases induced by the geometric shape and orientational interaction of the rod-blocks. A variety of liquid crystalline bilayers, corresponding to the smectic phases in bulk systems, are predicted to occur as equilibrium phases of the system. The ordered morphologies and phase behaviour of the system are analyzed. Phase diagrams of the self-assembled bilayers are constructed. The theoretical results provide an understanding of the formation mechanisms of these intricate phases.
使用自洽场理论研究了由棒-环嵌段共聚物自组装形成的双层膜的结构和相行为，重点关注棒-块的几何形状和取向相互作用诱导产生的液晶相的出现和相对稳定性。预测各种液晶双层膜作为体系的平衡相出现，对应于体相中的近晶相。分析了体系的有序形态和相行为。构建了自组装双层膜的相图。理论结果提供了对这些复杂相形成机制的理解。
