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中子射线照相法测量砂浆中盐溶液的吸收情况

NEUTRON RADIOGRAPHY MEASUREMENT OF SALT SOLUTION ABSORPTION IN MORTAR.

作者信息

Lucero Catherine L, Spragg Robert P, Bentz Dale P, Hussey Daniel S, Jacobson David L, Weiss W Jason

出版信息

ACI Mater J. 2017 Jan 1;114(1):149-159. doi: 10.14359/51689488.

Abstract

Some concrete pavements in the US have recently exhibited premature joint deterioration. It is hypothesized that one component of this damage can be attributed to a reaction that occurs when salt-laden water is absorbed in the concrete and reacts with the matrix. This study examines the absorption of CaCl solution in mortar via neutron imaging. Mortar specimens were prepared with water to cement ratios, (), of 0.36, 0.42 and 0.50 by mass and exposed to chloride solutions with concentrations ranging from 0 % to 29.8 % by mass. Depth of fluid penetration and moisture content along the specimen length were determined for 96 h after exposure. At high salt concentration (29.8 %), the sorption rate decreased by over 80 % in all samples. Along with changes in surface tension and viscosity, CaCl reacts with the cement paste to produce products (Friedel's salt, Kuzel's salt, or calcium oxychloride) that block pores and reduce absorption.

摘要

美国一些混凝土路面最近出现了过早的接缝劣化。据推测,这种损坏的一个原因可能是当含盐的水被混凝土吸收并与基体发生反应时所发生的一种反应。本研究通过中子成像研究了CaCl溶液在砂浆中的吸收情况。制备了水灰比()分别为0.36、0.42和0.50(质量比)的砂浆试件,并将其暴露于质量浓度范围为0%至29.8%的氯化物溶液中。在暴露96小时后,测定了沿试件长度方向的流体渗透深度和含水量。在高盐浓度(29.8%)下,所有样品的吸附率下降了80%以上。随着表面张力和粘度的变化,CaCl与水泥浆反应生成堵塞孔隙并减少吸收的产物(Friedel盐、Kuzel盐或氯氧化钙)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/17dc/5470119/a952bf8051db/nihms859723f1.jpg

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