Hu Xunliang, Xiao Zicheng, Huang Bo, Hu Xiaokang, Cheng Min, Lin Xinjun, Wu Pingfan, Wei Yongge
Institute of POM-based Materials, Hubei Province Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan, 430068, China.
Dalton Trans. 2017 Jul 4;46(26):8505-8513. doi: 10.1039/c7dt01543g.
A new synthetic approach to tri-substituted trisalkoxy-hexavanadate clusters containing different organic groups was developed in this work. Four mixed-valence or fully reduced POV hybrids were synthesized and structurally characterized, including an amino-containing derivative of hexavanadate, Na[VVO{NHC(CHO)}] (1). Furthermore, a novel mixed-valence POV hybrid was prepared via the amidation of 1, indicating that 1 can be used as an excellent building block for the design and synthesis of mixed-valence POV functional materials.
