Jiang Ruyong, Yang Xiuguang, Wu Di
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China.
Org Biomol Chem. 2017 Aug 23;15(33):6888-6891. doi: 10.1039/c7ob01344b.
The direct C-H activation of electron-deficient aza-BODIPYs has been effectively achieved via a concise and inexpensive Cu(ii)-promoted oxidative C-H/C-H coupling approach. The resulting indole-aza-BODIPY 6b covers a broad spectrum of 429-900 nm with a FWHM of 294 nm in solution and covers a UV-vis-NIR region up to 1100 nm in film.
通过一种简洁且经济的铜（II）促进的氧化C-H/C-H偶联方法，有效地实现了缺电子氮杂BODIPY的直接C-H活化。所得的吲哚-氮杂BODIPY 6b在溶液中的光谱范围为429-900 nm，半高宽为294 nm，在薄膜中覆盖高达1100 nm的紫外-可见-近红外区域。
