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一种新型磷酸镁NaRbMg(PO)的合成与晶体结构

Synthesis and crystal structure of a new magnesium phosphate NaRbMg(PO).

作者信息

Ben Hamed Teycir, Boukhris Amal, Badri Abdessalem, Ben Amara Mongi

机构信息

Unité de recherche, Matériaux Inorganiques, Faculté des Sciences, Université de Monastir, 5019, Monastir, Tunisia.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 May 5;73(Pt 6):817-820. doi: 10.1107/S2056989017006363. eCollection 2017 Jun 1.

DOI:10.1107/S2056989017006363
PMID:28638634
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5458299/
Abstract

A new magnesium phosphate, NaRbMg(PO) [tris-odium rubidium hepta-magnesium hexakis(ortho-phosphate)], has been synthesized as single crystals by the flux method and exhibits a new structure type. Its original structure is built up from MgO ( = 5 and 6) polyhedra linked directly to each other through common corners or edges and reinforced by corner-sharing with PO tetra-hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [010] direction, in which the Na cations are located, while the Rb cations are located in large inter-stitial cavities.

摘要

一种新的磷酸镁，NaRbMg(PO) [三钠铷七镁六（正磷酸）]，已通过助熔剂法合成出单晶，并呈现出一种新的结构类型。其原始结构由MgO （ = 5和6）多面体通过公共角或边直接相互连接而成，并通过与PO四面体共用角来加强。由此产生的阴离子三维骨架导致沿[010]方向形成通道，Na阳离子位于其中，而Rb阳离子位于大的间隙空腔中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/cd133f6835bc/e-73-00817-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/f16d176904ae/e-73-00817-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/6dbaca13805a/e-73-00817-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/168c0c879ebc/e-73-00817-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/cd133f6835bc/e-73-00817-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/f16d176904ae/e-73-00817-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/6dbaca13805a/e-73-00817-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/168c0c879ebc/e-73-00817-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2019/5458299/cd133f6835bc/e-73-00817-fig4.jpg

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