硝基官能化金属有机框架的热分解途径
Thermal decomposition pathways of nitro-functionalized metal-organic frameworks.
作者信息
McDonald Kyle A, Ko Nakeun, Noh Kyungkyou, Bennion Jonathan C, Kim Jaheon, Matzger Adam J
机构信息
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA.
出版信息
Chem Commun (Camb). 2017 Jul 6;53(55):7808-7811. doi: 10.1039/c7cc03354k.
PMID:28653067
Abstract
The decomposition behavior of high energy metal-organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both the structural metal and intimate mixing are found to be critical.
摘要
揭示了具有广泛硝化作用的高能金属有机框架（MOF）的分解行为。与分子高能化合物中观察到的爆轰行为不同，爆燃将立方MOF转变为具有高度分散金属的各向异性碳结构。发现结构金属和紧密混合都至关重要。
Zotero 插件