Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, CO, 80309, USA.
Chemistry and Nanoscience Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA.
Top Curr Chem (Cham). 2017 Aug;375(4):69. doi: 10.1007/s41061-017-0156-1. Epub 2017 Jun 26.
Functional polymeric materials have seen their way into every facet of materials chemistry and engineering. In this review article, we focus on a promising class of polymers, poly(aryleneethynylene)s, by covering several of the numerous applications found thus far for these materials. Additionally, we survey the current synthetic strategies used to create these polymers, with a focus on the emerging technique of alkyne metathesis. An overview is presented of the most recent catalytic systems that support alkyne metathesis as well as the more useful alkyne metathesis reaction capable of synthesizing poly(aryleneethynylene)s.
功能高分子材料已经应用于材料化学和工程的各个方面。在这篇综述文章中，我们重点介绍了一类很有前途的聚合物，即聚芳基乙炔，涵盖了迄今为止这些材料的许多应用。此外，我们还调查了目前用于合成这些聚合物的策略，重点介绍了炔烃复分解的新兴技术。本文还概述了支持炔烃复分解的最新催化体系以及更有用的能够合成聚芳基乙炔的炔烃复分解反应。
