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基于结晶诱导酮式发射(CIKE)的具有白色发光的ESIPT活性有机化合物。

ESIPT-active organic compounds with white luminescence based on crystallization-induced keto emission (CIKE).

作者信息

Liu Huapeng, Cheng Xiao, Zhang Houyu, Wang Yue, Zhang Hongyu, Yamaguchi Shigehiro

机构信息

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.

出版信息

Chem Commun (Camb). 2017 Jul 6;53(55):7832-7835. doi: 10.1039/c7cc03758a.

DOI:10.1039/c7cc03758a
PMID:28653705
Abstract

Structurally simple pyrazole derivatives that exhibit excited-state intramolecular proton transfer (ESIPT) were synthesized. While these compounds displayed deep violet fluorescence in solution, in the crystalline state they showed white emission from the enol and keto forms.

摘要

合成了具有激发态分子内质子转移(ESIPT)的结构简单的吡唑衍生物。虽然这些化合物在溶液中呈现深紫色荧光,但在结晶状态下,它们显示出烯醇式和酮式的白色发射。

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