School of Civil and Building Engineering, Loughborough University, Loughborough LE11 3TU, UK E-mail:
Water Sci Technol. 2017 Jun;75(12):2852-2863. doi: 10.2166/wst.2017.164.
This paper compares conventional and microwave hydrothermal carbonization (HTC) of human biowaste (HBW) at 160 °C, 180 °C and 200 °C as a potential technology to recover valuable carbonaceous solid fuel char and organic-rich liquor. Also discussed are the influence of HTC heating methods and temperature on HBW processing conversion into solid fuel char, i.e. yield and post-HTC management, dewaterability rates, particle size distribution and the carbon and energy properties of solid fuel char. While HTC temperatures influenced all parameters investigated, especially yield and properties of end products recovered, heating source effects were noticeable on dewatering rates, char particle sizes and HBW processing/end product recovery rate and, by extension, energy consumed. The microwave process was found to be more efficient for dewatering processed HBW and for char recovery, consuming half the energy used by the conventional HTC method despite the similarity in yields, carbon and energy properties of the recovered char. However, both processes reliably overcame the heterogeneity of HBW, converting them into non-foul end products, which were easily dewatered at <3 seconds/g total solids (TS) (c.f. 50.3 seconds/g TS for a raw sample) to recover energy-densified chars of ≈17 MJ/kg calorific value and up to 1.4 g/l of ammonia concentration in recovered liquor.
本文比较了在 160°C、180°C 和 200°C 下,采用传统和微波水热碳化(HTC)技术处理人源生物废物(HBW),以回收有价值的碳质固体燃料炭和富含有机物的液体。文中还讨论了 HTC 加热方式和温度对 HBW 加工转化为固体燃料炭的影响,即产率和 HTC 后管理、脱水率、粒径分布以及固体燃料炭的碳和能量特性。虽然 HTC 温度影响所有研究参数,特别是最终产物的产率和特性,但加热源对脱水率、炭粒径以及 HBW 加工/最终产物回收率的影响更为显著,进而影响能量消耗。研究发现,微波工艺在处理 HBW 和回收炭方面更为高效,尽管两种工艺的产率、回收炭的碳和能量特性相似,但微波工艺的能耗仅为传统 HTC 方法的一半。然而,这两种工艺都可靠地克服了 HBW 的不均匀性,将其转化为不易散发异味的最终产物,易于在 <3 秒/克总固体(TS)(相比之下,原始样品为 50.3 秒/克 TS)的条件下进行脱水,从而回收出能量密集型炭,热值约为 17 MJ/kg,在回收液中可达到 1.4 克/升的氨浓度。