Marsh M L, Albrecht-Schmitt T E
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL, 32306 USA.
Dalton Trans. 2017 Jul 25;46(29):9316-9333. doi: 10.1039/c7dt00664k.
Recent investigations of the coordination chemistry and physical properties of berkelium (Z = 97) and californium (Z = 98) have revealed fundamental differences between post-curium elements and lighter members of the actinide series. This review highlights these developments and chronicles key findings and concepts from the last half-century that have helped usher in a new understanding of the evolution of electronic structure in the periodic table.
最近对锫（Z = 97）和锎（Z = 98）的配位化学和物理性质的研究揭示了锕系后元素与锕系较轻成员之间的根本差异。本综述重点介绍了这些进展，并记录了过去半个世纪的关键发现和概念，这些发现和概念有助于开启对元素周期表中电子结构演变的新认识。
