普鲁士蓝衍生合成中空多孔黄铁矿纳米颗粒作为高效染料敏化太阳能电池的无铂对电极。
Prussian Blue-Derived Synthesis of Hollow Porous Iron Pyrite Nanoparticles as Platinum-Free Counter Electrodes for Highly Efficient Dye-Sensitized Solar Cells.
作者信息
Chen Jeffrey E, Fan Miao-Syuan, Chen Yen-Lin, Deng Yu-Heng, Kim Jung Ho, Alamri Hatem R, Alothman Zeid A, Yamauchi Yusuke, Ho Kuo-Chuan, Wu Kevin C-W
机构信息
Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Rd., Taipei, 10617, Taiwan.
Department of NanoEngineering, University of California, San Diego, La Jolla, CA, 92093, USA.
出版信息
Chemistry. 2017 Sep 27;23(54):13284-13288. doi: 10.1002/chem.201702687. Epub 2017 Jul 31.
Iron pyrite has long been an attractive material for environmental and energy applications, but is hampered by a lack of control over morphology and purity. Hollow porous iron pyrite nanoparticles were synthesized by a direct sulfurization of iron oxide derived from Prussian blue. The high efficiencies of these hollow porous iron pyrite nanoparticles as effective dye-sensitized solar cell counter electrodes were demonstrated, with an efficiency of 7.31 %.
长期以来，黄铁矿一直是环境和能源应用领域颇具吸引力的材料，但因形态和纯度难以控制而受到限制。通过对普鲁士蓝衍生的氧化铁进行直接硫化，合成了中空多孔黄铁矿纳米颗粒。这些中空多孔黄铁矿纳米颗粒作为有效的染料敏化太阳能电池对电极，展现出了高效性，效率达7.31%。
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