无过渡金属、可见光介导的1,10-菲咯啉衍生配体体系的合成
Transition metal-free, visible-light mediated synthesis of 1,10-phenanthroline derived ligand systems.
作者信息
Edwards Alyn C, Geist Andreas, Müllich Udo, Sharrad Clint A, Pritchard Robin G, Whitehead Roger C, Harwood Laurence M
机构信息
School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
出版信息
Chem Commun (Camb). 2017 Jul 18;53(58):8160-8163. doi: 10.1039/c7cc03903d.
A broad range of 1,10-phenanthroline substrates was efficiently C-H functionalised, providing rapid, gram-scale access to substituted heteroaromatic cores of broad utility. Furthermore, this C-H functionalisation pathway was extended to the synthesis of previously inaccessible, ultra-soluble, 2,9-bis-triazinyl-1,10-phenanthroline (BTPhen) ligands for advanced nuclear fuel cycles.
一系列1,10-菲咯啉底物能够高效地进行C-H官能化反应，从而能够快速地以克级规模获得具有广泛用途的取代杂芳环核心。此外，这种C-H官能化途径还扩展到了用于先进核燃料循环的、以前无法获得的超溶性2,9-双三嗪基-1,10-菲咯啉（BTPhen）配体的合成。
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