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食用油的太赫兹时域光谱学。

Terahertz time-domain spectroscopy of edible oils.

作者信息

Dinovitser Alex, Valchev Dimitar G, Abbott Derek

机构信息

School of Electrical and Electronic Engineering, University of Adelaide, Adelaide, South Australia, 5005, Australia.

School of Engineering and Innovation, The Open University, Milton Keynes MK7 6AA, UK.

出版信息

R Soc Open Sci. 2017 Jun 28;4(6):170275. doi: 10.1098/rsos.170275. eCollection 2017 Jun.

DOI:10.1098/rsos.170275
PMID:28680681
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5493923/
Abstract

Chemical degradation of edible oils has been studied using conventional spectroscopic methods spanning the spectrum from ultraviolet to mid-IR. However, the possibility of morphological changes of oil molecules that can be detected at terahertz frequencies is beginning to receive some attention. Furthermore, the rapidly decreasing cost of this technology and its capability for convenient, measurement of material properties, raises the possibility of monitoring oil during cooking and processing at production facilities, and more generally within the food industry. In this paper, we test the hypothesis that oil undergoes chemical and physical changes when heated above the smoke point, which can be detected in the 0.05-2 THz spectral range, measured using the conventional terahertz time-domain spectroscopy technique. The measurements demonstrate a null result in that there is no significant change in the spectra of terahertz optical parameters after heating above the smoke point for 5 min.

摘要

人们已使用从紫外到中红外光谱范围的传统光谱方法对食用油的化学降解进行了研究。然而,在太赫兹频率下可检测到的油分子形态变化的可能性开始受到一些关注。此外,这项技术成本的迅速降低及其方便测量材料特性的能力,增加了在生产设施的烹饪和加工过程中,更广泛地说在食品工业中监测油的可能性。在本文中,我们检验了这样一个假设:当油加热到冒烟点以上时会发生化学和物理变化,这些变化可以在0.05 - 2太赫兹光谱范围内检测到,使用传统的太赫兹时域光谱技术进行测量。测量结果显示为零结果,即在加热到冒烟点以上5分钟后,太赫兹光学参数的光谱没有显著变化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/3d0359d28c00/rsos170275-g4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/bf76c3ee4f9f/rsos170275-g1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/85cf5e156b7e/rsos170275-g2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/7d7be5827e65/rsos170275-g3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/3d0359d28c00/rsos170275-g4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/bf76c3ee4f9f/rsos170275-g1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/85cf5e156b7e/rsos170275-g2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/7d7be5827e65/rsos170275-g3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8999/5493923/3d0359d28c00/rsos170275-g4.jpg

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本文引用的文献

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Food Chem. 2015 Nov 15;187:416-23. doi: 10.1016/j.foodchem.2015.04.046. Epub 2015 Apr 21.
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A unique quantitative method of acid value of edible oils and studying the impact of heating on edible oils by UV-Vis spectrometry.一种独特的食用油酸值定量分析方法及利用紫外可见光谱法研究食用油加热的影响。
Food Chem. 2015 Oct 15;185:326-32. doi: 10.1016/j.foodchem.2015.04.005. Epub 2015 Apr 9.
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Terahertz absorption spectra of Fatty acids and their analogues.
Sensors (Basel). 2022 Oct 31;22(21):8363. doi: 10.3390/s22218363.
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Terahertz Time-Domain Reconstruction of Coating Microstratigraphy on Gilded Surfaces.镀金表面涂层微地层的太赫兹时域重建
Materials (Basel). 2019 Nov 21;12(23):3822. doi: 10.3390/ma12233822.
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Non-destructive inspection of food and technical oils by terahertz spectroscopy.太赫兹光谱法在食品和技术油的无损检测中的应用。
Sci Rep. 2018 Dec 21;8(1):18025. doi: 10.1038/s41598-018-36151-3.
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Bare carbon electrodes as simple and efficient sensors for the quantification of caffeine in commercial beverages.裸碳电极作为用于定量测定商业饮料中咖啡因的简单高效传感器。
R Soc Open Sci. 2018 May 2;5(5):172146. doi: 10.1098/rsos.172146. eCollection 2018 May.
脂肪酸及其类似物的太赫兹吸收光谱
J Oleo Sci. 2011;60(7):339-43. doi: 10.5650/jos.60.339.
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Optical parameters of vegetable oil studied by terahertz time-domain spectroscopy.利用太赫兹时域光谱研究植物油的光学参数。
Appl Spectrosc. 2010 Feb;64(2):231-4. doi: 10.1366/000370210790619663.
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Sensing the hygroscopicity of polymer and copolymer materials using terahertz time-domain spectroscopy.
Appl Opt. 2009 Apr 20;48(12):2262-6. doi: 10.1364/ao.48.002262.
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Material thickness optimization for transmission-mode terahertz time-domain spectroscopy.透射式太赫兹时域光谱的材料厚度优化
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