Zhu Tiantian, Zhang Xiaoyan, Li Zhikai, Hsu Chih-Hao, Chen Wei, Miyoshi Toshikazu, Li Xiaohong, Yang Xiaoming, Tu Yingfeng, Li Christopher Y
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Chem Commun (Camb). 2017 Jul 20;53(59):8336-8339. doi: 10.1039/c7cc03195e.
We present here that in two-dimensional (2D) fullerene supramolecular liquid crystals (SLCs), the phase diagram and lamella thickness of SLCs and 2D crystals can be tuned by the flexible alkyl tail and spacer length, due to their different effects on enthalpy and entropy changes during SLC formation.
我们在此展示，在二维（2D）富勒烯超分子液晶（SLC）中，由于柔性烷基链尾和间隔长度对SLC形成过程中的焓变和熵变有不同影响，SLC和二维晶体的相图以及片层厚度可以通过它们进行调节。
