Oliveira Marcos L S, Navarro Orlando G, Crissien Tito J, Tutikian Bernardo F, da Boit Kátia, Teixeira Elba C, Cabello Juan J, Agudelo-Castañeda Dayana M, Silva Luis F O
Universidade do Vale do Rio do Sinos, ITT-Performance, Av. Unisinos, 950 - Cristo Rei, RS 93022-000, Brazil; Department of Civil and Environmental, Universidad de la Costa, Calle 58 #55 - 66, Barranquilla, Colombia.
Department of Civil and Environmental, Universidad de la Costa, Calle 58 #55 - 66, Barranquilla, Colombia.
Environ Res. 2017 Oct;158:450-455. doi: 10.1016/j.envres.2017.07.002. Epub 2017 Aug 1.
There are multiple elements which enable coal geochemistry: (1) boiler and pollution control system design parameters, (2) temperature of flue gas at collection point, (3) feed coal and also other fuels like petroleum coke, tires and biomass geochemistry and (4) fuel feed particle size distribution homogeneity distribution, maintenance of pulverisers, etc. Even though there is a large number of hazardous element pollutants in the coal-processing industry, investigations on micrometer and nanometer-sized particles including their aqueous colloids formation reactions and their behaviour entering the environment are relatively few in numbers. X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/ (Energy Dispersive Spectroscopy) EDS/ (selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS and granulometric distribution analysis were used as an integrated characterization techniques tool box to determine both geochemistry and nanomineralogy for coal fly ashes (CFAs) from Brazil´s largest coal power plant. Ultrafine/nano-particles size distribution from coal combustion emissions was estimated during the tests. In addition the iron and silicon content was determined as 54.6% of the total 390 different particles observed by electron bean, results aimed that these two particles represent major minerals in the environment particles normally. These data may help in future investigations to asses human health actions related with nano-particles.
(1)锅炉和污染控制系统设计参数;(2)收集点处的烟气温度;(3)原煤以及其他燃料,如石油焦、轮胎和生物质的地球化学性质;(4)燃料进料颗粒尺寸分布均匀性、磨煤机的维护等。尽管煤炭加工行业存在大量有害元素污染物,但对微米级和纳米级颗粒,包括其水胶体形成反应及其进入环境的行为的研究相对较少。X射线衍射(XRD)、高分辨率透射电子显微镜(HR-TEM)/(能量色散光谱)EDS/(选区衍射图)SAED、场发射扫描电子显微镜(FE-SEM)/EDS和粒度分布分析被用作综合表征技术工具箱,以确定巴西最大燃煤电厂粉煤灰(CFA)的地球化学性质和纳米矿物学。在测试过程中估计了煤燃烧排放物中的超细/纳米颗粒尺寸分布。此外,通过电子束观察到的390种不同颗粒中,铁和硅的含量占总量的54.6%,结果表明这两种颗粒通常是环境颗粒中的主要矿物。这些数据可能有助于未来评估与纳米颗粒相关的人类健康影响的研究。