Center for Bio-Inspired Energy Science, Northwestern University , 303 East Superior Street, 11th floor, Chicago, Illinois 60611-3015, United States.
Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.
ACS Nano. 2017 Jul 25;11(7):7148-7155. doi: 10.1021/acsnano.7b02995. Epub 2017 Jul 14.
Ratcheting is a mechanism that produces directional transport of particles by rectifying nondirectional energy using local asymmetries rather than a net bias in the direction of transport. In a flashing ratchet, an oscillating force (here, an AC field) is applied perpendicular to the direction of transport. In an effort to explore the properties of current experimentally realizable ratchet systems, and to design new ones, this paper describes classical simulations of a damped flashing ratchet that transports charged nanoparticles within a transport layer of finite, non-zero thickness. The thickness of the layer, and the decay of the applied field in the z-direction throughout that thickness, provide a mechanism of symmetry breaking in the system that allows the ratchet to produce directional transport using a temporally unbiased oscillation of the AC driving field, a sine wave. Sine waves are conveniently produced experimentally or harvested from natural sources but cannot produce transport in a 1D or pseudo-1D system. The sine wave drive produces transport velocities an order of magnitude higher than those produced by the common on/off drive, but lower than those produced by a temporally biased square wave drive (unequal durations of the positive and negative states). The dependence of the particle velocity on the thickness of the transport layer, and on the homogeneity of the oscillating field within the layer, is presented for all three driving schemes.
棘轮是一种通过利用局部不对称性而不是沿传输方向的净偏差来纠正非定向能量的机制,从而产生颗粒的定向传输。在闪烁棘轮中,振荡力(这里是交流场)垂直于传输方向施加。为了探索当前实验可实现的棘轮系统的特性并设计新的系统,本文描述了在具有有限非零厚度的传输层内运输带电纳米颗粒的阻尼闪烁棘轮的经典模拟。该层的厚度以及在该厚度范围内 z 方向上施加的场的衰减为系统提供了一种对称破坏机制,允许棘轮使用交流驱动场的非时间偏置振荡(正弦波)产生定向传输。正弦波在实验中很方便地产生或从自然源中收集,但不能在 1D 或伪 1D 系统中产生传输。正弦波驱动产生的传输速度比常见的开/关驱动产生的速度高一个数量级,但比时间偏置的方波驱动(正、负状态的持续时间不等)产生的速度低。对于所有三种驱动方案,都给出了粒子速度对传输层厚度和层内振荡场均匀性的依赖关系。