• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

植酸铁（III）金属凝胶作为无水、中温质子导体的原型。

Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor.

作者信息

Aiyappa Harshitha Barike, Saha Subhadeep, Wadge Pritish, Banerjee Rahul, Kurungot Sreekumar

机构信息

Physical/Materials Chemistry Division , CSIR-National Chemical Laboratory , Dr Homi Bhabha Road , Pune-411008 , India . Email:

Academy of Scientific and Innovative Research (AcSIR) , New Delhi , India.

出版信息

Chem Sci. 2015 Jan 1;6(1):603-607. doi: 10.1039/c4sc02294g. Epub 2014 Oct 2.

DOI:10.1039/c4sc02294g
PMID:28706627
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5491955/
Abstract

A proton conducting metallogel [FNPA; ferric nitrate (FN)-phytic acid (PA)] is synthesized by immobilizing a protogenic ligand (phytic acid) using iron(iii) nitrate in DMF. The xerogel shows high proton conductivity of 2.4 × 10 S cm at 120 °C, the best value known among all metal organic materials (MOMs). Marking the first such attempt in MOMs, an electrode made using the xerogel showed a power density of 0.94 mW cm at 0.6 V under dry fuel cell conditions.

摘要

通过在N,N-二甲基甲酰胺（DMF）中用硝酸铁（III）固定质子原性配体（植酸）合成了一种质子传导金属凝胶[FNPA；硝酸铁（FN）-植酸（PA）]。该干凝胶在120°C时显示出2.4×10 S cm的高质子传导率，这是所有金属有机材料（MOM）中已知的最佳值。在金属有机材料中首次进行这样的尝试，使用该干凝胶制成的电极在干燃料电池条件下，在0.6 V时的功率密度为0.94 mW cm 。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/23c3a86e9c9b/c4sc02294g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/9a3e23ff9352/c4sc02294g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/a98c64a6b165/c4sc02294g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/e7eec0155ccb/c4sc02294g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/23c3a86e9c9b/c4sc02294g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/9a3e23ff9352/c4sc02294g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/a98c64a6b165/c4sc02294g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/e7eec0155ccb/c4sc02294g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43b8/5491955/23c3a86e9c9b/c4sc02294g-f4.jpg

相似文献

1
Fe(iii) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor.植酸铁（III）金属凝胶作为无水、中温质子导体的原型。
Chem Sci. 2015 Jan 1;6(1):603-607. doi: 10.1039/c4sc02294g. Epub 2014 Oct 2.
2
Modulation of defects in metal organic gels to enhance anhydrous proton conduction from subzero to moderate temperature.调控金属有机凝胶中的缺陷以增强从零下温度到适中温度的无水质子传导
J Colloid Interface Sci. 2023 Nov 15;650(Pt A):19-27. doi: 10.1016/j.jcis.2023.06.134. Epub 2023 Jun 20.
3
Unique Proton Transportation Pathway in a Robust Inorganic Coordination Polymer Leading to Intrinsically High and Sustainable Anhydrous Proton Conductivity.在一个坚固的无机配位聚合物中存在独特的质子传输途径，从而导致内在的高且可持续的无水质子电导率。
J Am Chem Soc. 2018 May 16;140(19):6146-6155. doi: 10.1021/jacs.8b02598. Epub 2018 May 7.
4
Dual-Proton Conductor for Fuel Cells with Flexible Operational Temperature.用于具有灵活工作温度的燃料电池的双质子导体
Adv Mater. 2024 Apr;36(14):e2310584. doi: 10.1002/adma.202310584. Epub 2024 Jan 5.
5
Triethylenetetramine-Based Semiconducting Fe(III) Metallogel: Effective Catalyst for Aryl-S Coupling.基于三亚乙基四胺的半导体铁（III）金属凝胶：芳基-S偶联的有效催化剂。
ACS Omega. 2020 Feb 10;5(6):2680-2689. doi: 10.1021/acsomega.9b03194. eCollection 2020 Feb 18.
6
Anhydrous Superprotonic Conductivity in the Zirconium Acid Triphosphate ZrH (PO ).三磷酸氧锆酸铪（ZrH(PO )）中的无水超质子导电性。
Angew Chem Int Ed Engl. 2023 Apr 24;62(18):e202218421. doi: 10.1002/anie.202218421. Epub 2023 Mar 23.
7
Anhydrous phosphoric Acid functionalized sintered mesoporous silica nanocomposite proton exchange membranes for fuel cells.用于燃料电池的磷酸功能化烧结介孔硅纳米复合质子交换膜
ACS Appl Mater Interfaces. 2013 Nov 13;5(21):11240-8. doi: 10.1021/am403479t. Epub 2013 Oct 30.
8
Highly Conductive Polybenzimidazole Membranes at Low Phosphoric Acid Uptake with Excellent Fuel Cell Performances by Constructing Long-Range Continuous Proton Transport Channels Using a Metal-Organic Framework (UIO-66).通过使用金属有机框架（UIO-66）构建长程连续质子传输通道，在低磷酸吸收量下具有优异燃料电池性能的高导电性聚苯并咪唑膜。
ACS Appl Mater Interfaces. 2020 Sep 16;12(37):41350-41358. doi: 10.1021/acsami.0c10527. Epub 2020 Sep 1.
9
Two-in-one: inherent anhydrous and water-assisted high proton conduction in a 3D metal-organic framework.二合一：三维金属有机骨架中固有的无水和水辅助质子传导。
Angew Chem Int Ed Engl. 2014 Mar 3;53(10):2638-42. doi: 10.1002/anie.201309077. Epub 2013 Dec 16.
10
Metal-Organic Gels Based on a Bisamide Tetracarboxyl Ligand for Carbon Dioxide, Sulfur Dioxide, and Selective Dye Uptake.基于双酰胺四羧基配体的金属有机凝胶对二氧化碳、二氧化硫及选择性染料的吸附
ACS Appl Mater Interfaces. 2019 May 29;11(21):19654-19667. doi: 10.1021/acsami.9b04659. Epub 2019 May 16.

引用本文的文献

1
Development of a novel self-healing Zn(II)-metallohydrogel with wide bandgap semiconducting properties for non-volatile memory device application.用于非易失性存储器件应用的具有宽带隙半导体特性的新型自修复锌（II）金属水凝胶的开发。
Sci Rep. 2024 Jun 7;14(1):13109. doi: 10.1038/s41598-024-61870-1.
2
Exploration of a wide bandgap semiconducting supramolecular Mg(II)-metallohydrogel derived from an aliphatic amine: a robust resistive switching framework for brain-inspired computing.探索一种源自脂肪族胺的宽带隙半导体超分子镁（II）金属水凝胶：一种用于脑启发计算的强大电阻开关框架。
Sci Rep. 2023 Dec 15;13(1):22318. doi: 10.1038/s41598-023-48936-2.
3

本文引用的文献

1
MOFs as proton conductors--challenges and opportunities.MOFs 作为质子导体——挑战与机遇。
Chem Soc Rev. 2014 Aug 21;43(16):5913-32. doi: 10.1039/c4cs00093e.
2
Hydrogen bond and proton transport in acid-base complexes and amphoteric molecules by density functional theory calculations and 1H and 31P nuclear magnetic resonance spectroscopy.通过密度泛函理论计算和 1H 和 31P 核磁共振波谱研究酸碱配合物和两性分子中的氢键和质子传递。
J Phys Chem B. 2013 Dec 19;117(50):16345-55. doi: 10.1021/jp4094386. Epub 2013 Nov 27.
3
Proton-conducting supramolecular metallogels from the lowest molecular weight assembler ligand: a quote for simplicity.
Two novel low molecular weight gelator-driven supramolecular metallogels efficient in antimicrobial activity applications.
两种新型低分子量凝胶剂驱动的超分子金属凝胶在抗菌活性应用中表现高效。
RSC Adv. 2023 Nov 8;13(47):32842-32849. doi: 10.1039/d3ra05019j. eCollection 2023 Nov 7.
4
Iron phosphide anchored nanoporous carbon as an efficient electrode for supercapacitors and the oxygen reduction reaction.磷化铁锚定的纳米多孔碳作为超级电容器和氧还原反应的高效电极。
RSC Adv. 2019 Aug 13;9(43):25240-25247. doi: 10.1039/c9ra04326h. eCollection 2019 Aug 8.
5
Coordination polymer glass from a protic ionic liquid: proton conductivity and mechanical properties as an electrolyte.基于质子离子液体的配位聚合物玻璃：作为电解质的质子传导率和机械性能
Chem Sci. 2020 Apr 17;11(20):5175-5181. doi: 10.1039/d0sc01737j.
6
Hierarchical Porous Graphene-Iron Carbide Hybrid Derived From Functionalized Graphene-Based Metal-Organic Gel as Efficient Electrochemical Dopamine Sensor.源自功能化石墨烯基金属有机凝胶的分级多孔石墨烯-碳化铁杂化物作为高效电化学多巴胺传感器
Front Chem. 2020 Jul 30;8:544. doi: 10.3389/fchem.2020.00544. eCollection 2020.
7
Tunable Metallogels Based on Bifunctional Ligands: Precursor Metallogels, Spinel Oxides, Dye and CO Adsorption.基于双功能配体的可调谐金属凝胶：前体金属凝胶、尖晶石氧化物、染料及一氧化碳吸附
ACS Omega. 2020 Jul 8;5(28):17356-17366. doi: 10.1021/acsomega.0c01710. eCollection 2020 Jul 21.
8
Triethylenetetramine-Based Semiconducting Fe(III) Metallogel: Effective Catalyst for Aryl-S Coupling.基于三亚乙基四胺的半导体铁（III）金属凝胶：芳基-S偶联的有效催化剂。
ACS Omega. 2020 Feb 10;5(6):2680-2689. doi: 10.1021/acsomega.9b03194. eCollection 2020 Feb 18.
9
MIL-100(Al) Gels as an Excellent Platform Loaded with Doxorubicin Hydrochloride for pH-Triggered Drug Release and Anticancer Effect.MIL-100（铝）凝胶作为负载盐酸阿霉素的优良平台用于pH触发的药物释放和抗癌作用。
Nanomaterials (Basel). 2018 Jun 19;8(6):446. doi: 10.3390/nano8060446.
10
Light driven mesoscale assembly of a coordination polymeric gelator into flowers and stars with distinct properties.光驱动配位聚合物凝胶剂组装成具有不同性质的花状和星状结构。
Chem Sci. 2015 Nov 1;6(11):6583-6591. doi: 10.1039/c5sc02233a. Epub 2015 Aug 12.
质子传导超分子金属凝胶由最低分子量组装配体组成：为简洁起见引述。
Chemistry. 2013 Jul 15;19(29):9562-8. doi: 10.1002/chem.201204542. Epub 2013 Jun 7.
4
Characterization of supramolecular gels.超分子凝胶的特性。
Chem Soc Rev. 2013 Aug 21;42(16):6697-722. doi: 10.1039/c3cs60080g.
5
Ion conductivity and transport by porous coordination polymers and metal-organic frameworks.多孔配位聚合物和金属有机骨架的离子电导率和输运。
Acc Chem Res. 2013 Nov 19;46(11):2376-84. doi: 10.1021/ar300291s. Epub 2013 Jun 3.
6
A water-stable metal-organic framework with highly acidic pores for proton-conducting applications.一种水稳定的具有高酸性孔的金属有机骨架，可用于质子传导应用。
J Am Chem Soc. 2013 Jan 30;135(4):1193-6. doi: 10.1021/ja310435e. Epub 2013 Jan 14.
7
Recent advances in metallogels.金属凝胶的最新进展。
Chem Soc Rev. 2013 Feb 21;42(4):1540-67. doi: 10.1039/c2cs35354g. Epub 2013 Jan 8.
8
Imparting high proton conductivity to a metal-organic framework material by controlled acid impregnation.通过控制酸浸渍将高质子传导性赋予金属有机骨架材料。
J Am Chem Soc. 2012 Sep 26;134(38):15640-3. doi: 10.1021/ja305587n. Epub 2012 Sep 12.
9
Inherent proton conduction in a 2D coordination framework.二维配位框架中的固有质子传导。
J Am Chem Soc. 2012 Aug 1;134(30):12780-5. doi: 10.1021/ja304693r. Epub 2012 Jul 18.
10
Thixotropic hydrogel derived from a product of an organic solid-state synthesis: properties and densities of metal-organic nanoparticles.由有机固态合成产物衍生的触变水凝胶：金属有机纳米粒子的性质和密度。
J Am Chem Soc. 2011 Mar 16;133(10):3365-71. doi: 10.1021/ja106095w. Epub 2011 Feb 22.