Wang TianKun, Fu Tong, Chen Yuyan, Zhang Zhongyue
Opt Lett. 2017 Jul 15;42(14):2842-2845. doi: 10.1364/OL.42.002842.
The circular dichroism (CD) effect plays an important role in biological detection, analytical chemistry, and plasmonic sensing. Tilted 3D structures can generate CD signals under normal illumination. However, fabricating tilted 3D structures is complex and expensive. In this study, we fabricate a tilted U-shaped nanostructure (TUSN) on a polystyrene (PS) nanosphere through the glancing angle deposition method. One branch of the U-shaped nanostructure is tilted by raising a sheet of SiO on the PS nanosphere. And the CD signal of the TUSN is enhanced because the phase difference increases with increasing thickness of the SiO sheet. This work proposes a method for fabricating tilted nanostructures and elucidates the mechanism of the CD effect for future research.
圆二色性(CD)效应在生物检测、分析化学和等离子体传感中起着重要作用。倾斜的三维结构在正常光照下可以产生CD信号。然而,制造倾斜的三维结构复杂且昂贵。在本研究中,我们通过掠角沉积法在聚苯乙烯(PS)纳米球上制备了倾斜的U形纳米结构(TUSN)。U形纳米结构的一个分支通过在PS纳米球上提升一片SiO而倾斜。并且TUSN的CD信号增强,因为相位差随着SiO片厚度的增加而增大。这项工作提出了一种制造倾斜纳米结构的方法,并阐明了CD效应的机制,以供未来研究。