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人发衍生的高比表面积多孔碳材料对四环素类抗生素的吸附等温线和动力学。

Human hair-derived high surface area porous carbon material for the adsorption isotherm and kinetics of tetracycline antibiotics.

机构信息

Chemical Engineering Department, University of Baghdad, P.O. Box 47024, Aljadria, Baghdad, Iraq.

Forestry and Wood Technology Discipline, Khulna University, Khulna 9208, Bangladesh.

出版信息

Bioresour Technol. 2017 Nov;243:778-784. doi: 10.1016/j.biortech.2017.06.174. Epub 2017 Jul 1.

Abstract

In this work, a human hair-derived high surface area porous carbon material (HHC) was prepared using potassium hydroxide activation. The morphology and textural properties of the HHC structure, along with its adsorption performance for tetracycline (TC) antibiotics, were evaluated. HHC showed a high surface area of 1505.11m/g and 68.34% microporosity. The effects of most important variables, such as initial concentration (25-355mg/L), solution pH (3-13), and temperatures (30-50°C), on the HHC adsorption performance were investigated. Isotherm data analysis revealed the favorable application of the Langmuir model, with maximum TC uptakes of 128.52, 162.62, and 210.18mg/g at 30, 40, and 50°C, respectively. The experimental data of TC uptakes versus time were analyzed efficiently using a pseudo-first order model. Porous HHC could be an efficient adsorbent for eliminating antibiotic pollutants in wastewater.

摘要

在这项工作中,使用氢氧化钾活化法制备了一种源自人发的高比表面积多孔碳材料(HHC)。评估了 HHC 结构的形态和结构特性及其对四环素(TC)抗生素的吸附性能。HHC 表现出 1505.11m/g 的高表面积和 68.34%的微孔率。考察了初始浓度(25-355mg/L)、溶液 pH 值(3-13)和温度(30-50°C)等最重要变量对 HHC 吸附性能的影响。等温线数据分析表明,Langmuir 模型具有良好的应用前景,在 30、40 和 50°C 下,TC 的最大吸附量分别为 128.52、162.62 和 210.18mg/g。TC 吸附量随时间的实验数据通过拟一级模型得到了有效分析。多孔 HHC 可能是一种有效去除废水中抗生素污染物的吸附剂。

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